On the comparsion of additive-free HfB2-SiC ceramics sintered by reactive hot-pressing and spark plasma sintering (Contributo in atti di convegno)

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Label
  • On the comparsion of additive-free HfB2-SiC ceramics sintered by reactive hot-pressing and spark plasma sintering (Contributo in atti di convegno) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Alternative label
  • F. Monteverde, A. Bellosi (2005)
    On the comparsion of additive-free HfB2-SiC ceramics sintered by reactive hot-pressing and spark plasma sintering
    in 29th International Conference on Advanced Ceramics and Composites, Cocoa Beach, Florida, 23-28/01/20005
    (literal)
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  • F. Monteverde, A. Bellosi (literal)
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  • Fornito contributo orale \"Reactive hot-pressing of a HfB2-SiC composite\" (literal)
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  • Development in advanced ceramics and composites (literal)
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  • ISTEC-CNR (literal)
Titolo
  • On the comparsion of additive-free HfB2-SiC ceramics sintered by reactive hot-pressing and spark plasma sintering (literal)
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  • 1-57498-261-3 (literal)
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  • M. Brito, P. Filip, C. Lewinsohn, A. Sayir, M. Opeka, W.M. Mullin (literal)
Abstract
  • Ultra-high-temperature HfB2-SiC ceramics were produced by reactive hot-pressing (RHP) and spark plasma sintering (SPS) successfully. In the former case, a mixture of Hf/Si/B4C, mechanically mixed in molar ratio 2.2/0.8/1, was \"in-situ\" converted into HfB2 and SiC, and then directly hot-pressed until full density was achieved. In the SPS case, a powder mixture of HfB2 + 30vol% SiC was fully densified at 2,100°C, 100°C/min heating rate and 2 min dwell time. The microstructure in both the materials consisted of faceted diboride grains, finer in the RHP case, with SiC particles evenly distributed intergranularly. The combination of some thermo-mechanical properties was of considerable significance. Flexural strength of the RHP fabricated material measured at 25 °C and 1,500 °C in ambient air was 770?35 and 310?15 MPa, respectively. A relevant merit characterized fracture toughness and flexural strength of the material produced by SPS: the values measured at room temperature (3.9?0.3 MPa?m and 590?50 MPa, respectively) did not decrease appreciably at 1500 °C (4.0?0.1 MPa?m and 600?15 MPa, respectively). (literal)
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