Innovative M(hfa)2.TMEDA (M=Cu, Co) Precursors for the CVD of Copper-Cobalt Oxides: an Integrated Theoretical and Experimental Approach (Articolo in rivista)

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Label
  • Innovative M(hfa)2.TMEDA (M=Cu, Co) Precursors for the CVD of Copper-Cobalt Oxides: an Integrated Theoretical and Experimental Approach (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Alternative label
  • A. Gasparotto, D. Barreca, A. Devi, R.A. Fischer, E. Fois, A. Gamba, C. Maccato, R. Seraglia, G. Tabacchi, E. Tondello (2009)
    Innovative M(hfa)2.TMEDA (M=Cu, Co) Precursors for the CVD of Copper-Cobalt Oxides: an Integrated Theoretical and Experimental Approach
    in ECS transactions
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • A. Gasparotto, D. Barreca, A. Devi, R.A. Fischer, E. Fois, A. Gamba, C. Maccato, R. Seraglia, G. Tabacchi, E. Tondello (literal)
Pagina inizio
  • 549 (literal)
Pagina fine
  • 556 (literal)
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  • 25 (literal)
Rivista
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  • DOI: 10.1149/1.3207638 (literal)
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  • 8 (literal)
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  • 1,7,10: Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy 2,8: CNR-ISTM and INSTM, Department of Chemistry, Padova University, 35131 Padova, Italy 3,4: Inorganic Materials Chemistry Group, Lehrstuhl für Anorganische Chemie II, Ruhr-University Bochum, 44780 Bochum, Germany 5,6,9: Department of Chemical and Environmental Sciences, Insubria University and INSTM, 22100 Como, Italy (literal)
Titolo
  • Innovative M(hfa)2.TMEDA (M=Cu, Co) Precursors for the CVD of Copper-Cobalt Oxides: an Integrated Theoretical and Experimental Approach (literal)
Abstract
  • This work is focused on a joint experimental and theoretical characterization of M(hfa)2.TMEDA complexes [M=Cu, Co; hfa=1,1,1,5,5,5-hexafluoro-2,4-pentanedionate; TMEDA=N,N,N'’,N'’-tetramethylethylenediamine], innovative CVD precursors for Cu-Co oxides. The structural, vibrational and thermal properties of the above compounds, as well as their fragmentation pathways, have been thoroughly analyzed by Fourier Transform Infrared Spectroscopy (FT-IR), Electrospray Ionization Mass Spectrometry (ESI-MS) and tandem Mass Spectrometry (MS/MS), ThermoGravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC). Results obtained by the above techniques have been integrated by ab-initio Density Functional Theory (DFT) calculations. The most relevant results, with particular regard to CVD applications of the target compounds, are presented and discussed. (literal)
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