Toxicological characterization of the thermal decomposition products of chemicals: A new approach to an old problem (Articolo in rivista)

Type
Label
  • Toxicological characterization of the thermal decomposition products of chemicals: A new approach to an old problem (Articolo in rivista) (literal)
Anno
  • 2011-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.3303/CET1124188 (literal)
Alternative label
  • Roberto Sanchirico, Gabriele. Pinto, Antonino Pollio. Mauro Cordella, Valerio Cozzani (2011)
    Toxicological characterization of the thermal decomposition products of chemicals: A new approach to an old problem
    in Chemical Engineering transactions
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Roberto Sanchirico, Gabriele. Pinto, Antonino Pollio. Mauro Cordella, Valerio Cozzani (literal)
Pagina inizio
  • 1123 (literal)
Pagina fine
  • 1128 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 24 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • Proceedings of ICheAP-10, Firenze 8-11 maggio 2011 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto di Ricerche sulla Combustione (CNR); Università di Napoli \"Federico II\"; Università di Bologna (literal)
Titolo
  • Toxicological characterization of the thermal decomposition products of chemicals: A new approach to an old problem (literal)
Abstract
  • Different calorimetrie techniques coupled with chemical analyses and ecotoxicological bioassay led to the proposal of suitable protocol for the definition of a KPI (Key Process Index) useful to rank a compound in respect to the toxicological profile of its thermal decomposition products. Fenitrothion was used as example and showed to decompose through a seri es of two mai n processes, the first being less severe than the second. lt is demonstrated that similar ecotoxicological results can be gathered both using adiabatic and Isothermal conditions. This allows to exclude a priori the necessity of carrying out the more difficult and time and money consuming adiabatic experiments. The analytical characterization of the samples collected during a series of isoperibolic (quasi­ isothermal) experiments allowed to calculate, using the software ECOSAR, the toxicological profile of the intermediate compounds. (literal)
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