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Oxo-centered carboxylate-bridged trinuclear complexes deposited on Au(111) by a mass-selective electrospray (Articolo in rivista)
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- Label
- Oxo-centered carboxylate-bridged trinuclear complexes deposited on Au(111) by a mass-selective electrospray (Articolo in rivista) (literal)
- Anno
- 2011-01-01T00:00:00+01:00 (literal)
- Alternative label
Corradini V., C. Cervetti, A. Ghirri, R. Biagi, U. del Pennino, G.A. Timco, R.E.P. Winpenny, and M. Affronte (2011)
Oxo-centered carboxylate-bridged trinuclear complexes deposited on Au(111) by a mass-selective electrospray
in New journal of chemistry (1987)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Corradini V., C. Cervetti, A. Ghirri, R. Biagi, U. del Pennino, G.A. Timco, R.E.P. Winpenny, and M. Affronte (literal)
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- Funding: This work was partially funded by SEED project-INFM in 2008 and European STREP project MolSpinQIP (Molecular Spin Clusters for Quantum Information Processing), contract No. 211284. (literal)
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- - CNR, Inst Nanosci S3, I-41125 Modena, Italy (V. Corradini, C. Cervetti, A. Ghirri, R. Biagi, U. del Pennino, M. Affronte)
- Univ Modena & Reggio Emilia, Dipartimento Fis, I-41125 Modena, Italy(V. Corradini, C. Cervetti, A. Ghirri, R. Biagi, U. del Pennino, M. Affronte)
- Univ Manchester, Sch Chem, Lewis Magnetism Lab, Manchester M13 9PL, Lancs, England (G.A. Timco, R.E.P. Winpenny) (literal)
- Titolo
- Oxo-centered carboxylate-bridged trinuclear complexes deposited on Au(111) by a mass-selective electrospray (literal)
- Abstract
- We explored the possibility to deposit Molecular NanoMagnets (metallorganic complexes) by electrospray. To this end, we developed an apparatus for nondestructive in vacuum deposition of fragile molecular complexes, by modifying a commercial Mass Spectrometer equipped with an electrospray ionization source. Starting from solution, this system creates a beam of ionized molecules which is then transferred into an evacuated region where molecules can be mass selected before deposition. To check the system efficiency, we deposited sub monolayers of oxo-centered carboxylate-bridged trinuclear complexes (Cr(3) and Cr(2)Ni) on the Au(111) surface. By XPS and STM we determined the deposited molecule stoichiometry and the surface coverage. Results show that this type of apparatus works well for the in vacuum deposition of molecular nanomagnets and, thanks to the reduced dimensions, it is portable and adaptable to facilities requiring UHV. (literal)
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