The catalytic activity of FeOx/ZrO2 and FeOx/sulphated-ZrO2 for the NO abatement with C3H6 in the presence of excess O2 (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• The catalytic activity of FeOx/ZrO2 and FeOx/sulphated-ZrO2 for the NO abatement with C3H6 in the presence of excess O2 (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.apcatb.2005.02.016 (literal)

Alternative label

• Indovina V., Campa M.C., Pepe F., Pietrogiacomi D., Tuti S. (2005)
  The catalytic activity of FeOx/ZrO2 and FeOx/sulphated-ZrO2 for the NO abatement with C3H6 in the presence of excess O2
  in Applied catalysis. B, Environmental (Print); Elsevier, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Indovina V., Campa M.C., Pepe F., Pietrogiacomi D., Tuti S. (literal)

Pagina inizio

• 23 (literal)

Pagina fine

• 31 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0926337305001037 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 60 (literal)

Rivista

• Applied catalysis. B, Environmental (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• fasc. (1-2). Elsevier. (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 9 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1-2 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• a) Dipartimento di Chimica, Università di Roma \"La Sapienza\", Piazzale Aldo Moro 5, 00185 Roma, Italy b) Sezione ''MICE'' dell'Istituto I.S.C. (CNR), c/o Dipartimento di Chimica, Universita` di Roma ''La Sapienza'', Piazzale Aldo Moro 5, 00185 Roma, Italy c) Centro C.I.S.Di.C., c/o Dipartimento di Ingegneria Meccanica e Industriale, Università degli Studi \"Roma Tre\", Via della Vasca Navale 79, 00146 Roma, Italy d) Dipartimento di Ingegneria Meccanica e Industriale, Università degli Studi \"Roma Tre\", Italy (literal)

Titolo

• The catalytic activity of FeOx/ZrO2 and FeOx/sulphated-ZrO2 for the NO abatement with C3H6 in the presence of excess O2 (literal)

Abstract

• Iron containing catalysts were prepared by (i) impregnation of ZrO2 with aqueous solutions of Fe(NO3)3, Fe/Zi, or aqueous solutions of NH4Fe(SO4)2, FeS/Z; (ii) chemical vapour deposition (CVD) of FeCl3 on ZrO2, Fe/ZCVD; and (iii) impregnation of sulphated-ZrO2 with toluene solutions of Fe(acetylacetonate)3, Fe/SZ. After calcining at 823 K, samples were characterised by temperature-programmed reduction with H2 and Fourier transformed IR spectroscopy. NO reduction with C3H6 in the presence of excess O2 was studied in a flow apparatus fed by a reactant mixture of NO:C3H6:O2 = 2000 ppm:2000 ppm (or 2700 ppm):20,000 ppm in He. FTIR characterisation by CO adsorption showed that various carbonyl-like species formed on Fen+ sites (0 <= n < 3). Their relative amounts depended not on the iron content, but on the catalyst preparation method. The reducibility of FeIII to FeII in H2 increased in the order FeS/Z < Fe/ZCVD < Fe/Zi. In the C3H6 + O2 reaction, the catalytic activity for C3H6 oxidation increased in parallel with the reducibility. In the NO + C3H6 + O2 reaction, the selectivity to CO2 (rather than to CO) increased in parallel with the reducibility. By contrast, the selectivity of C3H6 towards NO rather than O2 increased in the reverse order. These results suggest that the catalytic activity and selectivity of the various samples depend on the chemical behaviour of the FeIII/FeII redox couple. (literal)

Editore

• Elsevier (Editore)

Prodotto di

• Materiali inorganici complessi per catalisi eterogenea. (Bio)sensori. (MD.P02.005.002) (Modulo)

Autore CNR

• MARIA CRISTINA CAMPA (Persona)

Insieme di parole chiave

• Keywords of "The catalytic activity of FeOx/ZrO2 and FeOx/sulphated-ZrO2 for the NO abatement with C3H6 in the presence of excess O2" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• MARIA CRISTINA CAMPA (Persona)

Prodotto

• Materiali inorganici complessi per catalisi eterogenea. (Bio)sensori. (MD.P02.005.002) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. B, Environmental (Rivista)

Editore di

• Elsevier (Editore)

Insieme di parole chiave di

• Keywords of "The catalytic activity of FeOx/ZrO2 and FeOx/sulphated-ZrO2 for the NO abatement with C3H6 in the presence of excess O2" (Insieme di parole chiave)