http://www.cnr.it/ontology/cnr/individuo/prodotto/ID56200
Isothermal vapour + liquid equilibrium measurements and correlation for the pentafluoroethane + cyclopropane and the cyclopropane + 1,1,1,2-tetrafluoroethane binary systems (Articolo in rivista)
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- Isothermal vapour + liquid equilibrium measurements and correlation for the pentafluoroethane + cyclopropane and the cyclopropane + 1,1,1,2-tetrafluoroethane binary systems (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.fluid.2006.10.023 (literal)
- Alternative label
Fedele L.; Bobbo S.; Camporese R.; Scattolini M. (2007)
Isothermal vapour + liquid equilibrium measurements and correlation for the pentafluoroethane + cyclopropane and the cyclopropane + 1,1,1,2-tetrafluoroethane binary systems
in Fluid phase equilibria; ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
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- Fedele L.; Bobbo S.; Camporese R.; Scattolini M. (literal)
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- Presentato alla \"17th European Conference on Thermophysical properties, 8-10 settembre 2005, Bratislava, Repubblica Slovacca\" (literal)
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- Consiglio Nazionale delle Ricerche, Istituto per le Tecnologie della Costruzione, Sede di Padova, Corso Stati Uniti 4, 35127 Padova, Italy (literal)
- Titolo
- Isothermal vapour + liquid equilibrium measurements and correlation for the pentafluoroethane + cyclopropane and the cyclopropane + 1,1,1,2-tetrafluoroethane binary systems (literal)
- Abstract
- Isothermal vapour + liquid equilibria data were measured for the binary systems pentafluoroethane + cyclopropane and cyclopropane + 1,1,1,2-tetrafluoroethane at 253.15, 273.15 and 293 15 K, using a static analytical method. The phase compositions at equilibrium were measured by gas chromatography. The experimental estimated accuracies are ±0.02K for temperature, ±1 kPa for pressure, and ±0.003 in mole fraction for both liquid and vapour phase composition. Both systems show strong positive deviations from Raoult's law with the formation of an azeotrope. The experimental data were regressed using the Peng-Robinson-Stryjek-Vera equation of state, with different mixing rules, i.e. theVan derWaals mixing rule with one or two interaction parameters, and Huron-Vidal and Wong-Sandler mixing rules. A comparison with literature data was performed. (literal)
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