Optimization of the MnCeOx system for the catalytic wet oxidation of phenol with oxygen (CWAO) (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Optimization of the MnCeOx system for the catalytic wet oxidation of phenol with oxygen (CWAO) (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.apcatb.2008.06.020 (literal)

Alternative label

• Francesco Arena; Giuseppe Trunfio; Jacopo Negro; Lorenzo Spadaro (2008)
  Optimization of the MnCeOx system for the catalytic wet oxidation of phenol with oxygen (CWAO)
  in Applied catalysis. B, Environmental (Print); ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS, AMSTERDAM (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Francesco Arena; Giuseppe Trunfio; Jacopo Negro; Lorenzo Spadaro (literal)

Pagina inizio

• 40 (literal)

Pagina fine

• 47 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 85 (literal)

Rivista

• Applied catalysis. B, Environmental (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1-2 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento di Chimica Industriale e Ingegneria dei Materiali, Universita` degli Studi di Messina, Salita Sperone 31 c.p. 29, I-98166 S. Agata (Messina), Italy Istituto CNR-ITAE ''Nicola Giordano'', Salita S. Lucia 5, I-98126 S. Lucia (Messina), Italy (literal)

Titolo

• Optimization of the MnCeOx system for the catalytic wet oxidation of phenol with oxygen (CWAO) (literal)

Abstract

• A class of MnCeC(x) catalysts has been synthesized via the new redox-precipitation route in alternative to the conventional co-precipitation technique. The effects of preparation method, composition and calcination temperature on catalyst texture, dispersion and reduction pattern properties have been addressed. Redox-precipitated systems exhibit high surface area (SA, 120-170 m(2)/g), large pore volume (PV, 0.4-0.5 cm(3)/g) and a \"narrow\" pore size distribution (PSD) in a wide range of the Mn/Ce ratio (1/3-3/1). A quasi-molecular dispersion markedly improves oxide-support interactions and reducibility of the active phase. Redox-precipitated systems show a superior performance in the catalytic wet oxidation of phenol with oxygen (CWAO) at 373 K in terms of substrate and total organic carbon (TOC) elimination and mineralization (i.e., CO(2) formation) selectivity. Carbon mass-balance from TG-DSC data of used catalysts and CO(2) selectivity values signal that the CWAO of phenol proceeds via a L-H reaction path, the oxidation of C-containing species being the rate limiting step (r.l.s.). Then, an optimum average pore diameter (APD. 10-15 nm) enhances the rate of the adsorption step, while a straight relation between CO(2) selectivity and reducibility prove that dispersion and redox properties of the active phase control the mineralization activity of the MnCeCx system (literal)

Editore

• ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS (Editore)

Prodotto di

• Produzione di combustibili sintetici da sorgenti fossili e da CO2 (ET.P02.005.001) (Modulo)
• Institute for advanced energy technologies \"Nicola Giordano\" (ITAE) (Istituto)

Autore CNR

• LORENZO SPADARO (Unità di personale interno)

Incoming links:

Autore CNR di

• LORENZO SPADARO (Unità di personale interno)

Prodotto

• Institute for advanced energy technologies \"Nicola Giordano\" (ITAE) (Istituto)
• Produzione di combustibili sintetici da sorgenti fossili e da CO2 (ET.P02.005.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. B, Environmental (Rivista)

Editore di

• ELSEVIER SCIENCE BV, PO BOX 211, 1000 AE AMSTERDAM, NETHERLANDS (Editore)