http://www.cnr.it/ontology/cnr/individuo/prodotto/ID55143

Catalytic Polymer membranes under forcing conditions: reduction of nitrobenzene by CO/H2O catalyzed by ruthenium bis(arylimino) acenaphthene complexes (Articolo in rivista)

Type

Articolo in rivista (Classe)
Prodotto della ricerca (Classe)

Label

Catalytic Polymer membranes under forcing conditions: reduction of nitrobenzene by CO/H2O catalyzed by ruthenium bis(arylimino) acenaphthene complexes (Articolo in rivista) (literal)

Anno

2010-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

10.1002/cctc.201000044 (literal)

Alternative label

Viganò M., Ragaini F., Buonomenna M.G., Lariccia R., Caselli A., Gallo E., Cenini S., Jansen J.C., Drioli E., (2010)
Catalytic Polymer membranes under forcing conditions: reduction of nitrobenzene by CO/H2O catalyzed by ruthenium bis(arylimino) acenaphthene complexes
in ChemCatChem (Print); Wiley-VCH - Weinheim, Wheinheim (Germania)
(literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

Viganò M., Ragaini F., Buonomenna M.G., Lariccia R., Caselli A., Gallo E., Cenini S., Jansen J.C., Drioli E., (literal)

Pagina inizio

1150 (literal)

Pagina fine

1164 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

http://www.scopus.com/inward/record.url?eid=2-s2.0-79957725819&partnerID=tZOtx3y1 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

2 (literal)

Rivista

ChemCatChem (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

9 (literal)

Note

Scopus (literal)
ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

Dipartimento di Chimica Inorganica, Metallorganica e Analitica Lamberto Malatesta, Università di Milano, and ISTM-CNR, Via Venezian 21, 20133 Milano, (Italy); ITM-CNR, c/o Università della Calabria, Via P. Bucci, 87036, Rende (CS) (Italy); Dipartimento di Ingegneria Chimica e dei Materiali, Università della Calabria, Via P. Bucci, 87036, Rende (CS) (Italy) (literal)

Titolo

Catalytic Polymer membranes under forcing conditions: reduction of nitrobenzene by CO/H2O catalyzed by ruthenium bis(arylimino) acenaphthene complexes (literal)

Abstract

Polymeric membranes embedding a metal complex have been previously employed as reusable catalysts under relatively mild conditions. Herein, the first example of a polymeric catalytic membrane employed under very forcing conditions (160 °C and 5 MPa CO) is reported. The reaction investigated was the reduction of nitrobenzene to aniline by CO/H2O, catalyzed by ruthenium bis(arylimino)acenaphthene (Ar-BIAN) complexes. To better retain the complex in the membrane, a modified ligand, with long alkyl chains in the para positions of the aryl rings, was prepared. Among several polymers tested as membranes, PEEK-WC, a modified polyether ether ketone, gave the best results. Attempts to embed the ligand only in the membrane and functionalize it with the metal later, analogously to the in situ generation of the active species practiced for the homogeneous system, failed and it was necessary to synthesize new complexes that could be reduced under the reaction conditions. Best results were obtained using [Ru(Ar-BIAN)(CO)2Cl2]+Et3N. During the reaction, the complex is transformed into a mixture of [Ru3(CO)12] and a reduced form of the ligand, Ar-BIANH2. The latter was independently prepared and shown to be able to reduce nitrobenzene even in the absence of any metal. A new kind of support was designed to allow the placing of the membrane in a stirred autoclave. Using only water as solvent, no metal or ligand leaching was detected and several recycles were performed. All employed membranes were thoroughly characterized by different techniques. (literal)

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