Combined Emulsion and Phase Inversion Techniques for the Preparation of Catalytic PVDF Microcapsules (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Combined Emulsion and Phase Inversion Techniques for the Preparation of Catalytic PVDF Microcapsules (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/jp804897b (literal)

Alternative label

• Buonomenna, M. G., Figoli, A., Spezzano, I., Morelli, R., Drioli, E. (2008)
  Combined Emulsion and Phase Inversion Techniques for the Preparation of Catalytic PVDF Microcapsules
  in The journal of physical chemistry. B
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Buonomenna, M. G., Figoli, A., Spezzano, I., Morelli, R., Drioli, E. (literal)

Pagina inizio

• 11264 (literal)

Pagina fine

• 11269 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 112 (literal)

Rivista

• ?The ?journal of physical chemistry. B (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Institute on Membrane Technology (ITM-CNR), c/o University of Calabria, via P.Bucci, 87030 Rende (CS), Italy (literal)

Titolo

• Combined Emulsion and Phase Inversion Techniques for the Preparation of Catalytic PVDF Microcapsules (literal)

Abstract

• In this work, polyvinilydene fluoride (PVDF) microcapsules were prepared by using combined emulsion and phase inversion techniques. With this method, microcapsules with different diameters and porosities have been obtained by just controlling the diameter of the membrane used during the preparation. Using a PVDF solution containing the oxidation catalyst ammonium molybdate (20 wt %), catalytic polymeric microcapsules with diameters ranging from 600 to 1200 ?m have been obtained. Characterization of catalytic microcapsules by means of SEM, BSE, and EDX analyses showed a uniform ammonium molybdate dispersion in the polymeric matrix. Catalytic microcapsules have been tested in the oxidation of aromatic primary alcohols to corresponding aldehydes. In the range 600-1200 ?m, the microcapsule diameter influences the formation of oxidation products: in particular, microcapsule diameters > 900 ?m slightly diminish the formation of aldehyde due to a beginning diffusion limitation. An interesting structure-reactivity behavior, induced by the interaction between the polymeric membrane and the substituted aromatic alcohol, has been observed. (literal)

Prodotto di

• Simulazioni e modellistica di fenomeni di trasporto in membrane ed operazioni a membrana per mezzo dei metodi della chimica computazionale (PM.P02.007.002) (Modulo)
• Institute on membrane technology (ITM) (Istituto)

Autore CNR

• ALBERTO FIGOLI (Unità di personale interno)
• MARIA GIOVANNA BUONOMENNA (Persona)
• ENRICO DRIOLI (Unità di personale esterno)

Incoming links:

Prodotto

• Institute on membrane technology (ITM) (Istituto)
• Simulazioni e modellistica di fenomeni di trasporto in membrane ed operazioni a membrana per mezzo dei metodi della chimica computazionale (PM.P02.007.002) (Modulo)

Autore CNR di

• ALBERTO FIGOLI (Unità di personale interno)
• ENRICO DRIOLI (Unità di personale esterno)
• MARIA GIOVANNA BUONOMENNA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• ?The ?journal of physical chemistry. B (Rivista)