http://www.cnr.it/ontology/cnr/individuo/prodotto/ID54940
A porous stainless steel supported silica membrane for WGS reaction in a catalytic membrane reactor (Articolo in rivista)
- Type
- Label
- A porous stainless steel supported silica membrane for WGS reaction in a catalytic membrane reactor (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.ces.2007.01.054 (literal)
- Alternative label
Brunetti, A., Barbieri, G., Drioli, E., Granato, T., Lee, K.-H. (2007)
A porous stainless steel supported silica membrane for WGS reaction in a catalytic membrane reactor
in Chemical engineering science
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Brunetti, A., Barbieri, G., Drioli, E., Granato, T., Lee, K.-H. (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
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- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Institute for Membrane Technology ITM-CNR, Via Pietro BUCCI, c/o The University of Calabria, Cubo 17/C, 87030 Rende, CS, Italy
Department of Chemical Engineering and Materials, The University of Calabria, Via Pietro BUCCI, Cubo 44/A, 87030 Rende, CS, Italy
Membrane and Separation Research Center, Korea Research Institute of Chemical Technology (KRICT), 305-600 Daejeon, South Korea (literal)
- Titolo
- A porous stainless steel supported silica membrane for WGS reaction in a catalytic membrane reactor (literal)
- Abstract
- In this work the water gas shift (WGS) reaction in a membrane reactor (MR) using a porous stainless steel supported silica membrane and
a CuO/CeO2 based commercial catalyst was analysed in a temperature range of 220-290 oC up to 600 kPa. The reaction pressure effect on
the CO conversion and permeate stream composition was followed with special attention paid to the significant performance improvement in
the MR. The best operating condition for the MR was identified as 280 oC and 400 kPa, obtaining a CO conversion of 95% with an increment
of 8% with respect to TR.
Furthermore, the membrane permeance (H2 : 9.7.29; CO : 0.3.1.1; CO2: 0.4.1.5 nmol/m2 s Pa) and selectivity (H2/CO, H2/CO2 ranging
from 15 to 40) and the influence of other gases on H2 permeation were evaluated before and after reaction testing. No inhibition effect of other
gases on the hydrogen flux in all cases was observed. An MR using silica membranes was successfully employed in the WGS reaction, obtaining
always higher conversion than with a traditional reactor (TR) and also (at T >250 oC) exceeding the TR equilibrium conversion (TREC). (literal)
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