Highly Chemoselective Hydrogenation of 2-Ethylanthraquinone to Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed Inside Very Lipophilic Functional Resins (Articolo in rivista)

Type
Label
  • Highly Chemoselective Hydrogenation of 2-Ethylanthraquinone to Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed Inside Very Lipophilic Functional Resins (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Biffis A., Ricoveri R., Campestrini S., Kralik M., Jer`Bek K., Corain B. (2002)
    Highly Chemoselective Hydrogenation of 2-Ethylanthraquinone to Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed Inside Very Lipophilic Functional Resins
    in European journal of organic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Biffis A., Ricoveri R., Campestrini S., Kralik M., Jer`Bek K., Corain B. (literal)
Pagina inizio
  • 2962 (literal)
Pagina fine
  • 2967 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 8 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Highly Chemoselective Hydrogenation of 2-Ethylanthraquinone to Ethylanthrahydroquinone Catalyzed by Palladium Metal Dispersed Inside Very Lipophilic Functional Resins (literal)
Abstract
  • Most hydrogen peroxide is currently produced by the selective hydrogenation of 2-ethylanthraquinone to 2-ethylanthrahydroquinone, followed by tratment with dioxygen: this produces hydrogen peroxide and regenerates 2-ethylanthraquinone We have developed novel catalysts for this process that are based on palladium supported on very lipophilic functional resins and that are able to promote a chemioselectivity for 2- ethylanthrahydroquinone slightly but definitely superior to that provided by an industrial catalyst under identical conditions. This finding demonstrates the potential of variations of the lipophilic/hydrophilic character of the support as a tool for the improvement of the chemoselectivity of resin-based metal catalysts. (literal)
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