http://www.cnr.it/ontology/cnr/individuo/prodotto/ID54573
N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene (Articolo in rivista)
- Type
- Label
- N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.reactfunctpolym.2010.10.001 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Yang HW; Luan SF; Zhao J; Shi HC; Shi QA ; Yin JH; Stagnaro P (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://www.sciencedirect.com/science/article/pii/S1381514810001756 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
CNR, Ist Studio Macromol, I-16149 Genoa, Italy (literal)
- Titolo
- N-vinyl pyrrolidone-assisted free radical functionalization of glycidyl methacrylate onto styrene-b-(ethylene-co-butylene)-b-styrene (literal)
- Abstract
- N-vinyl pyrrolidone (NVP)-assisted free radical functionalization of glycidyl methacrylate (GMA) onto styrene-b-(ethylene-co-butylene)-b-styrene (SEBS) was investigated to attempt to overcome the low grafting reactivity of GMA and the low efficiency of the styrene (St)-assisted functionalization method. By using the optimal amount of NVP, the degree of GMA grafting was increased by at least 7.5 and 2.5-fold when compared to GMA alone and the St-assisted grafting procedure, respectively. Also, no apparent cross-linking or degradation reactions of SEBS were observed. It was proposed that NVP reacted first with SEBS macroradicals, and then the resulting NVP-macroradicals copolymerized with GMA to produce high degrees of grafting of both GMA and NVP onto SEBS. (C) 2010 Elsevier Ltd. All rights reserved. (literal)
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