New fluorinated montmorillonites for the preparation of UV-cured coatings (Articolo in rivista)

Type
Label
  • New fluorinated montmorillonites for the preparation of UV-cured coatings (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.jcis.2009.04.053 (literal)
Alternative label
  • Di Gianni A.; Bongiovanni R.; Conzatti L.; Turri S. (2009)
    New fluorinated montmorillonites for the preparation of UV-cured coatings
    in Journal of colloid and interface science (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Di Gianni A.; Bongiovanni R.; Conzatti L.; Turri S. (literal)
Pagina inizio
  • 455 (literal)
Pagina fine
  • 461 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S0021979709004779 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 336 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 2 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Di Gianni A., Bongiovanni R. - Politecnico di Torino; Conzatti L. - CNR ISMAC Genova; Turri S. - Politecnico di Milano (literal)
Titolo
  • New fluorinated montmorillonites for the preparation of UV-cured coatings (literal)
Abstract
  • Montmorillonite was modified by means of a cation exchange reaction with two fluorinated ammonium salts, containing either a fluoroalkylic or a perfluoropolyether chain. The introduction of the fluorinated ammonium salts into the clay mineral galleries led in both cases to an increase of the interlayer distance, as revealed from the XRD spectra. However, the surfactant conformation achieved was different: a double layer Structure was formed by the fluoroalkylic modifier, a paraffinic structure was present when the perfluoropolyether surfactant was used. This led to different results when the organoclays were dispersed into a typical UV curable dimethacrylate: a good degree of intercalation was achieved only with the clay modified by the fluoroalkylic surfactant. (literal)
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