Polypropylene modified with 2-hydroxyethyl acrylate-g-2-methacryloyloxyethyl phosphorylcholine and its hemocompatibility (Articolo in rivista)

Type
Label
  • Polypropylene modified with 2-hydroxyethyl acrylate-g-2-methacryloyloxyethyl phosphorylcholine and its hemocompatibility (Articolo in rivista) (literal)
Anno
  • 2010-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.apsusc.2010.05.028 (literal)
Alternative label
  • Zhao J; Shi QA; Yin LG; Luan SF; Shi HC; Song LG; Yin JH; Stagnaro P (2010)
    Polypropylene modified with 2-hydroxyethyl acrylate-g-2-methacryloyloxyethyl phosphorylcholine and its hemocompatibility
    in Applied surface science
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Zhao J; Shi QA; Yin LG; Luan SF; Shi HC; Song LG; Yin JH; Stagnaro P (literal)
Pagina inizio
  • 7071 (literal)
Pagina fine
  • 7076 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://www.sciencedirect.com/science/article/pii/S0169433210007087 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 256 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 23 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Zhao J; Shi QA; Yin LG; Luan SF; Shi HC; Song LG; Yin JH, Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China Stagnaro P, CNR ISMAC Genova (literal)
Titolo
  • Polypropylene modified with 2-hydroxyethyl acrylate-g-2-methacryloyloxyethyl phosphorylcholine and its hemocompatibility (literal)
Abstract
  • Polypropylene (PP) was modified with 2-hydroxyethyl acrylate (HEA) by solution radical grafting to introduce active hydroxyl groups on polypropylene backbone (PP-g-HEA). Then the biomimic monomer, 2-methacryloyloxyethyl phosphorycholine (MPC), was grafted onto the surface of PP-g-HEA film (PP-g-HEA-g-MPC) by redox graft polymerizations with ceric(IV) ammonium nitrate as an initiator. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) showed that the HEA and MPC were introduced onto PP molecular chains and the copolymer, PP-g-HEA-g-MPC were formed. The water contact angle measurements demonstrated that the final modified PP film exhibited a better hydrophilic surface compared to the neat PP film. The platelets adhesion on the neat PP, PP-g-HEA and PP-g-HEA-g-MPC film was examined by scanning electron microscopy (SEM). It was found that a large number of platelets were adhered and activated on the surface of neat PP and PP-g-HEA films, while the number of platelets on PP-g-HEA-g-MPC surface was decreased remarkably. The result revealed that the introduction of poly(MPC) onto the PP surface improved the hemocompatibility of PP substantially. (C) 2010 Elsevier B.V. All rights reserved. (literal)
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