Addition polymerisations of bicyclo[3.2.0]hept-6-ene and bicyclo[4.2.0]-oct-7-ene with early and late transition metal compounds (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Addition polymerisations of bicyclo[3.2.0]hept-6-ene and bicyclo[4.2.0]-oct-7-ene with early and late transition metal compounds (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/macp.200700597 (literal)

Alternative label

• Curran K.; Risse W.; Boggioni L.; Tritto I. (2008)
  Addition polymerisations of bicyclo[3.2.0]hept-6-ene and bicyclo[4.2.0]-oct-7-ene with early and late transition metal compounds
  in Macromolecular chemistry and physics (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Curran K.; Risse W.; Boggioni L.; Tritto I. (literal)

Pagina inizio

• 707 (literal)

Pagina fine

• 714 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/doi/10.1002/macp.200700597/pdf (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 209 (literal)

Rivista

• Macromolecular chemistry and physics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 7 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• L. Boggioni, I. Tritto ISMAC—MILANO K. Curran, W. Risse University College Dublin, UCD School of Chemistry and Chemical Biology, Belfield, Dublin 4, Ireland (literal)

Titolo

• Addition polymerisations of bicyclo[3.2.0]hept-6-ene and bicyclo[4.2.0]-oct-7-ene with early and late transition metal compounds (literal)

Abstract

• Bicyclo[3.2.0]hept-6-ene was converted into the corresponding addition polymer poly(6,7-bicyclo[3.2.0]heptylene) with the aid of early and late transition metal based olefin polymerisation catalysts. Moderate to very good yields (42-99%) of polymer were obtained with [Pd(NCEt)(4)][BF4](2), [(eta(3)-allyl)Pd(solv(2))(2)][SbF6], [(2,9-dimethyl-1,10-phenanthroline)Pd(CH3)(NC(CH2)(6)CH3)][SbF6], and Cp2ZrCl2/MAO, using monomer to transition metal ratios between 50/1 and 250/1. Reaction occurs at the olefin pi-bond, and the four-membered ring of the monomer is retained during polymerisation which differs from ring-opening olefin metathesis polymerisation in which the four-membered ring is opened. The nearly exclusively saturated structure of the polymer was confirmed by H-1 and C-13 NMR spectroscopy. It is proposed that the polymers consist of repeating units that are predominantly cis-exo-enchained. GPC analysis of the soluble polymers prepared with [Pd(NCEt)(4)][BF4](2) showed that molecular mass values (M) over bar (n)(GPC) were in the range of 3 700 to 22 600. (literal)

Prodotto di

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)

Autore CNR

• LAURA BOGGIONI (Persona)
• INCORONATA TRITTO (Persona)

Insieme di parole chiave

• Parole chiave di "Addition polymerisations of bicyclo[3.2.0]hept-6-ene and bicyclo[4.2.0]-oct-7-ene with early and late transition metal compounds" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• LAURA BOGGIONI (Persona)
• INCORONATA TRITTO (Persona)

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Catalisi per nuove architetture macromolecolari e sistemi polimerici nanostrutturati e biomimetici (PM.P02.005.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Macromolecular chemistry and physics (Rivista)

Insieme di parole chiave di

• Parole chiave di "Addition polymerisations of bicyclo[3.2.0]hept-6-ene and bicyclo[4.2.0]-oct-7-ene with early and late transition metal compounds" (Insieme di parole chiave)