A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/adfm.200600470 (literal)

Alternative label

• Yunus S.; Delcorte A.; Poleunis C.; Bertrand P.; Bolognesi A.; Botta C. (2007)
  A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging
  in Advanced functional materials (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Yunus S.; Delcorte A.; Poleunis C.; Bertrand P.; Bolognesi A.; Botta C. (literal)

Pagina inizio

• 1079 (literal)

Pagina fine

• 1084 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://apps.webofknowledge.com/OutboundService.do?&SID=2Ak93@CKiLi36gj3C7m&publisher_id=DOISource&toPID=DOISource&URL=http%3A%2F%2Fgateway.webofknowledge.com%2Fgateway%2FGateway.cgi%3FGWVersion%3D2%26SrcAuth%3DDOISource%26SrcApp%3DWOS%26KeyAID%3D10.1002%252Fadfm.200600470%26DestApp%3DDOI%26SrcAppSID%3D2Ak93%40CKiLi36gj3C7m%26SrcJTitle%3DADVANCED%2520FUNCTIONAL%2520MATERIALS&product=WOS&action=go&mode=transferToPublisher&highlighted_tab=WOS&colName=WOS (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 17 (literal)

Rivista

• Advanced functional materials (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 7 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• S. Yunus, A. Delcorte, C. Poleunis, P. Bertrand, Laboratoire de Physico-Chimie et de Physique des Materiaux, Universite Catholique de Louvain, Belgium A. Bolognesi, C. Botta. ISMAC CNR (literal)

Titolo

• A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging (literal)

Abstract

• A new type of polymer compound that allows the formation of highly ordered microstructured films by casting from a volatile solvent in the presence of humidity, and its characterization by ToF-SIMS (time-of-flight secondary-ion mass spectrometry) are presented. A honeycomb structure is obtained by activation of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO)-terminated polystyrene (PS) with p-toluenesulfonic acid (PTSA). The mechanism of this activation reaction, leading to a more polar PS termination, is deduced from simple experiments and supported by ToF-SIMS characterization. Positive and negative ToF-SIMS imaging allows different chemical regions correlating to the film morphology to be distinguished. This new, straightforward activation process, together with ToF-SIMS chemical imaging, provides a better understanding of the phenomena underlying the formation of these films by directly linking the role of polar terminations to the microscale self-organization. This new method, transposable to other organic acids, suggests interesting new perspectives in the field of self-organized chemical and topographical patterning (literal)

Prodotto di

• Nano/Microsistemi organici, ibridi per optoelettronica (PM.P04.001.006) (Modulo)
• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)

Autore CNR

• CHIARA BOTTA (Persona)
• ALBERTO BOLOGNESI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Nano/Microsistemi organici, ibridi per optoelettronica (PM.P04.001.006) (Modulo)

Autore CNR di

• CHIARA BOTTA (Persona)
• ALBERTO BOLOGNESI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Advanced functional materials (Rivista)

Insieme di parole chiave di

• Parole chiave di "A route to self-organized honeycomb microstructured polystyrene films and their chemical characterization by ToF-SIMS imaging" (Insieme di parole chiave)