Synthesis and crystal structure and optical properties of fluorenic-core oligomers (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Synthesis and crystal structure and optical properties of fluorenic-core oligomers (Articolo in rivista) (literal)

Anno

• 2002-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/B109089P (literal)

Alternative label

• Destri S., Pasini M., Botta C., Porzio W., Bertini F., Marchiò L. (2002)
  Synthesis and crystal structure and optical properties of fluorenic-core oligomers
  in Journal of materials chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Destri S., Pasini M., Botta C., Porzio W., Bertini F., Marchiò L. (literal)

Pagina inizio

• 924 (literal)

Pagina fine

• 933 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.rsc.org/en/content/articlepdf/2002/jm/b109089p (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 12 (literal)

Rivista

• Journal of materials chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica delle Macromolecole del C.N.R; Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma (literal)

Titolo

• Synthesis and crystal structure and optical properties of fluorenic-core oligomers (literal)

Abstract

• Fluorenic core oligomers, displaying interesting PL properties, have been synthesized by organometallic route. The crystal and molecular structure of a fluorene derivative and three omologous oligomers has been studied. Spiro-derivative of fluorene dibromine shows a very strong interaction among H and Br atoms. The thienyl ending oligomer with spiro-substituent adopt a particular herring-bone arrangement with overlap of only end-thienyl residues, conformationally disordered. The crystal of all-phenyl derivative consists of the packing of discrete molecules cofacially arranged. The molecule with linear alkyl chains onto the 9 position of fluorenic core and thienyl ring as end-group exhibits polymorphism and its crystal structure, tetragonal, is very peculiar because of the unclose packing allowing a good separation among adjacent thienyl rings.The absorption and emission properties of this series were investigated and the electroluminescence of single- layer devices was characterized. The PL properties of the molecules are strongly dependent on their structural organization, displaying a red-shift of the emission from the amorphous phase, to the crystalline structure, to the aggregated form. A comparison of the packing of these oligomers and oligothienylenes fully accounts for the optical properties of the reported molecules. (literal)

Prodotto di

• Materiali multifunzionali organici e ibridi per l'energia (PM.P04.001.007) (Modulo)
• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)

Autore CNR

• MARIACECILIA PASINI (Persona)
• CHIARA BOTTA (Persona)
• WILLIAM UMBERTO PORZIO (Unità di personale interno)
• FABIO BERTINI (Unità di personale interno)
• SILVIA MARIA DESTRI (Unità di personale interno)

Incoming links:

Autore CNR di

• MARIACECILIA PASINI (Persona)
• SILVIA MARIA DESTRI (Unità di personale interno)
• CHIARA BOTTA (Persona)
• FABIO BERTINI (Unità di personale interno)
• WILLIAM UMBERTO PORZIO (Unità di personale interno)

Prodotto

• Istituto per lo studio delle macromolecole (ISMAC) (Istituto)
• Materiali multifunzionali organici e ibridi per l'energia (PM.P04.001.007) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of materials chemistry (Rivista)