http://www.cnr.it/ontology/cnr/individuo/prodotto/ID53765
Gold nanoparticles modified GC electrodes: electrochemical behaviour dependence of different neurotransmitters and molecules of biological interest on the particles size and shape (Articolo in rivista)
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- Gold nanoparticles modified GC electrodes: electrochemical behaviour dependence of different neurotransmitters and molecules of biological interest on the particles size and shape (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s11051-008-9547-0 (literal)
- Alternative label
Caschera Daniela (1); Federici Fulvio (1) ; Zane Daniela (2); Focanti Francesca (2); Curulli Antonella (2); Padeletti Giuseppina (1); (2009)
Gold nanoparticles modified GC electrodes: electrochemical behaviour dependence of different neurotransmitters and molecules of biological interest on the particles size and shape
in Journal of nanoparticle research; Springer, Dordrecht (Paesi Bassi)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Caschera Daniela (1); Federici Fulvio (1) ; Zane Daniela (2); Focanti Francesca (2); Curulli Antonella (2); Padeletti Giuseppina (1); (literal)
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- http://www.springerlink.com/content/q18727814j2q/ (literal)
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- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1) ISMN-CNR, Via Salaria Km 29,300, 00016, Monterotondo Scalo, Roma, Italy;
2) ISMN-CNR, Via Castro Laurenziano 7, Rome, Italy; (literal)
- Titolo
- Gold nanoparticles modified GC electrodes: electrochemical behaviour dependence of different neurotransmitters and molecules of biological interest on the particles size and shape (literal)
- Abstract
- Gold colloidal nanoparticles (AuNps),
synthesized by gold chloride hydrate (HAuCl4)
chemical reduction were used to realize a modified
glassy carbon electrode (GCE). Different shapes and
sizes were observed, varying the molar ratio of
HAuCl4 and polyvinylpyrrolidone (PVP). The electrochemical
behaviour of different neurotransmitters
and molecules of biological interest (dopamine,
caffeic acid, catechol, uric acid, epinephrine and
serotonin) were investigated by cyclic voltammetry
(CV) at the AuNps modified GCE and a dependence
of the electrochemical response on the size and the
shape of the particles was observed. The electrochemical
responses were stable during time with a
generic decreasing of the peak current after 10 days
ranging from 5-10% for catechol, uric acid and
serotonine to 10-15% for the other analytes. A study
on the electrochemical interface of modified electrodes
was also carried out by means of
electrochemical impedance spectroscopy (EIS). (literal)
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