http://www.cnr.it/ontology/cnr/individuo/prodotto/ID53724
Support effect of the catalytic performance of Au/Co3O4-CeO2 catalysts for CO and CH4 oxidation (Articolo in rivista)
- Type
- Label
- Support effect of the catalytic performance of Au/Co3O4-CeO2 catalysts for CO and CH4 oxidation (Articolo in rivista) (literal)
- Anno
- 2008-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.cattod.2008.04.025 (literal)
- Alternative label
L. F. Liotta, , G. Di Carlo, A. Longo, G. Pantaleo, A. M. Venezia (2008)
Support effect of the catalytic performance of Au/Co3O4-CeO2 catalysts for CO and CH4 oxidation
in Catalysis Today
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- L. F. Liotta, , G. Di Carlo, A. Longo, G. Pantaleo, A. M. Venezia (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto per lo Studio di Materiali Nanostrutturati, CNR, Via Ugo La Malfa, 153, 90146 Palermo, Italy
Dipt. Chimica Inorganica e Analitica, ''S. Cannizzaro'', Universita` di Palermo, V.le delle Scienze, Parco D'Orleans, 90128 Palermo, Italy (literal)
- Titolo
- Support effect of the catalytic performance of Au/Co3O4-CeO2 catalysts for CO and CH4 oxidation (literal)
- Abstract
- Gold-based catalysts supported on Co3O4, on CeO2 and on mixed Co3O4-CeO2 oxides were prepared by
co-precipitation. They were tested in the catalytic oxidation of CO and CH4, in separate tests, and their
activities were compared with that of the bare oxides. Tests of CH4 oxidation were performed in two
consecutive runs in order to evaluate the catalysts stability. The effect of SO2 in the reactant mixture was
investigated. The fresh and spent catalysts were analsed by XRD, BET, TPR and XPS techniques. Among the
fresh catalysts, Au supported on CeO2 was the most active in CO oxidation whereas Au supported on
Co3O4 was the most active for methane total oxidation. Synergy between the two oxides was not
observed for gold on mixed Co3O4-CeO2 system. However, in consecutive runs of methane oxidation and
in the presence of SO2, Au supported on mixed Co3O4-CeO2 exhibited higher stability and superior SO2
tolerance as compared to the single oxide catalysts. (literal)
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