Relative energy and structural differences of axial andequatorial 1-fluoro-1-silacyclohexane (Articolo in rivista)

Type
Label
  • Relative energy and structural differences of axial andequatorial 1-fluoro-1-silacyclohexane (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1021/jp061583n (literal)
Alternative label
  • Laura B. Favero; Biagio Velino; Walther Caminati; Ingvar Árnason; Ágúst Kvaran (2006)
    Relative energy and structural differences of axial andequatorial 1-fluoro-1-silacyclohexane
    in The journal of physical chemistry. A
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Laura B. Favero; Biagio Velino; Walther Caminati; Ingvar Árnason; Ágúst Kvaran (literal)
Pagina inizio
  • 9995 (literal)
Pagina fine
  • 9999 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 110 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 33 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto per lo Studio dei Materiali Nanostrutturati (ISMN, Sezione di Bologna), CNR, Via Gobetti 101, I-40129 Bologna, Italy; Dipartimento di Chimica Fisica e Inorganica dell'UniVersita` di Bologna,Viale Risorgimento 4, I-40136 Bologna, Italy; Dipartimento di Chimica \"G. Ciamician\" dell'UniVersita` di Bologna, Via Selmi 2, I-40126 Bologna, Italy; Science Institute, UniVersity of Iceland, Dunhaga 3, 107 ReykjaV?´k, Iceland; Science Institute, UniVersity of Iceland, Dunhaga 3, 107 ReykjaV?´k, Iceland; (literal)
Titolo
  • Relative energy and structural differences of axial andequatorial 1-fluoro-1-silacyclohexane (literal)
Abstract
  • The rotational spectra of the main isotopomer, of the Si-29 and of all C-13 isotopologues of axial and equatorial forms of 1-fluoro-silacyclohexane have been measured by conventional ( only main species) and molecular beam Fourier transform microwave spectroscopy. r(0) and partial r(s) structures are given separately for the two forms. The main structural differences are discussed. From dipole moments and relative intensity measurements, a slight preference (E-Eq - E-Ax 42 +/- 24 cm(-1)) for the axial conformer was found. The rotational spectra of some, the most intense, vibrational satellites have also been measured. They belong to the ring-puckering motions. (literal)
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