Dehydrogenation of glycerol to dihydroxyacetone catalyzed by iridium complexes with P–N ligands (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Dehydrogenation of glycerol to dihydroxyacetone catalyzed by iridium complexes with P–N ligands (Articolo in rivista) (literal)

Anno

• 2010-01-01T00:00:00+01:00 (literal)

Alternative label

• Crotti C., Kaspar J., Farnetti E. (2010)
  Dehydrogenation of glycerol to dihydroxyacetone catalyzed by iridium complexes with P–N ligands
  in Green chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Crotti C., Kaspar J., Farnetti E. (literal)

Pagina inizio

• 1295 (literal)

Pagina fine

• 1300 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 12 (literal)

Rivista

• Green chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• http://dx.doi.org/10.1039/c003542d (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Struttura della Materia - CNR; Consorzio Interuniversitario \"Chimica per l'Ambiente\", unità di ricerca Trieste Dipartimento di Scienze Chimiche, Università di Trieste (literal)

Titolo

• Dehydrogenation of glycerol to dihydroxyacetone catalyzed by iridium complexes with P–N ligands (literal)

Abstract

• The chemoselective dehydrogenation of glycerol was catalyzed by organoiridium derivatives of the type [HIr(cod)L] (cod = 1,5-cyclooctadiene; L = Prn-N(CH2CH2PPh2)2, Et2NCH2CH2N(CH2CH2PPh2)2, o-Me2NC6H4PPh2) using hydrogen acceptors such as acetophenone, cyclohexanone, styrene and benzaldehyde. The catalytic reactions were performed in the absence of a basic cocatalyst in order to avoid decomposition of the desired product, i.e. dihydroxyacetone. Acceptor-less dehydrogenation was also observed either in the absence of a hydrogen acceptor, or as a parallel route, when the reaction was performed in the presence of acetophenone (literal)

Prodotto di

• Institute of structure of matter (ISM) (Istituto)
• Proprietà magnetiche, elettroniche e funzionali di aggregati di dimensione atomica (MD.P04.004.001) (Modulo)

Autore CNR

• CORRADO CROTTI (Unità di personale interno)

Incoming links:

Autore CNR di

• CORRADO CROTTI (Unità di personale interno)

Prodotto

• Institute of structure of matter (ISM) (Istituto)
• Proprietà magnetiche, elettroniche e funzionali di aggregati di dimensione atomica (MD.P04.004.001) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Green chemistry (Rivista)