Hydrogen trasfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials (Articolo in rivista)

Type
Label
  • Hydrogen trasfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Milani B., Crotti C., Farnetti E. (2008)
    Hydrogen trasfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials
    in Dalton transactions (2003. Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Milani B., Crotti C., Farnetti E. (literal)
Pagina inizio
  • 4659 (literal)
Pagina fine
  • 4663 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 34 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • http://dx.doi.org/10.1039/b807259k (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR - ISM Università di Trieste (literal)
Titolo
  • Hydrogen trasfer reduction of polyketones catalyzed by iridium complexes: a novel route towards more biocompatible materials (literal)
Abstract
  • Transfer hydrogenation from 2-propanol to CO/4-methylstyrene and CO/styrene polyketones was catalyzed by [Ir(diene)(N-N)X] (N-N = nitrogen chelating ligand; X = halogen) in the presence of a basic cocatalyst. The reactions were performed using dioxane as cosolvent, in order to overcome problems due to low polyketone solubility. The polyalcohols were obtained in yields up to 95%, the conversions being markedly dependent on the nature of the ligands coordinated to iridium as well as on the experimental conditions. (literal)
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