In situ dispersive x-ray reflectometry to investigate the (RuPc)2/NOx interaction process evidenced by ex situ measurements (Articolo in rivista)

Type
Label
  • In situ dispersive x-ray reflectometry to investigate the (RuPc)2/NOx interaction process evidenced by ex situ measurements (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1063/1.2171778 (literal)
Alternative label
  • Generosi A. 1; Paci B. 1; Rossi Albertini V. 1; Perfetti P. 1; Paoletti A.M. 2; Pennesi G. 2; Rossi G. 2; Caminiti R. 3 (2006)
    In situ dispersive x-ray reflectometry to investigate the (RuPc)2/NOx interaction process evidenced by ex situ measurements
    in Journal of applied physics
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Generosi A. 1; Paci B. 1; Rossi Albertini V. 1; Perfetti P. 1; Paoletti A.M. 2; Pennesi G. 2; Rossi G. 2; Caminiti R. 3 (literal)
Pagina inizio
  • 044901 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 99 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • http://dx.doi.org/10.1063/1.2171778 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1 Istituto di Struttura della Materia-Area di Ricerca di Tor Vergata, Via del Fosso del Cavaliere 100, 00133 Roma, Italy; 2 Istituto di Struttura della Materia-Area di Ricerca di Montelibretti, Via Salaria Km. 29.5, Casclla Portale 10 Monterotondo Stazione, I-00016 Roma, Italy; 3 Dipartimento di Chimica, Università “La Sapienza” di Roma e sezione INFM, Piazale Aldo Moro 5, 00185 Roma, Italy (literal)
Titolo
  • In situ dispersive x-ray reflectometry to investigate the (RuPc)2/NOx interaction process evidenced by ex situ measurements (literal)
Abstract
  • A systematic energy dispersive x-ray reflectometry study of different ruthenium phthalocyanine (RuPc)2 thin films was performed in order to investigate their reactivity with the oxidizing NOx gas. A preliminary ex situ analysis, consisting of the comparison between the morphological parameters of different films (before and after the exposure to the gas), was performed. It suggests that a reaction involving two different mechanisms takes place. The following in situ (while fluxing the gas) reflectometry analysis confirms this hypothesis, and clarifies the temporal evolution, also revealing that the first mechanism is limited to the film surface, while the second is a bulk diffusion process. (literal)
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