Photochemical and structural properties of the cyclodextrin inclusion complexes of aryl-olefin bichromophores (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Photochemical and structural properties of the cyclodextrin inclusion complexes of aryl-olefin bichromophores (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jphotochem.2005.04.014 (literal)

Alternative label

• S. Monti, F. Manoli, I. Manet, G. Marconi, B. Mayer, R. E. Tormos, M. A. Miranda, (2005)
  Photochemical and structural properties of the cyclodextrin inclusion complexes of aryl-olefin bichromophores
  in Journal of photochemistry and photobiology. A, Chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• S. Monti, F. Manoli, I. Manet, G. Marconi, B. Mayer, R. E. Tormos, M. A. Miranda, (literal)

Pagina inizio

• 349 (literal)

Pagina fine

• 357 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 173 (literal)

Rivista

• Journal of photochemistry and photobiology. A, Chemistry (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 9 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 3 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• S. Monti, F. Manoli, I. Manet, G. Marconi: isof-cnr (literal)

Titolo

• Photochemical and structural properties of the cyclodextrin inclusion complexes of aryl-olefin bichromophores (literal)

Abstract

• The photoproducts distribution of 2-allylphenol (1), 2-allylanisole (2) and 2-allylaniline (3) were strongly modified by inclusion of these compounds in cyclodextrin (CD) cavities. Under these conditions photocyclization for 1 and 3 and di-pi-methane photorearrangement for 2, occurring in homogeneous solvents, were strongly depressed and photohydration of the acyclic olefin moiety was found to be by far the predominating photoprocess. The determination of the stability constants, the absorption properties, the steady state and time resolved fluorescence, the induced circular dichroism, accompanied by conformational calculations, of the CD complexes of 1-3, allowed a rationale to be reached for the modified photochemical behavior of these compounds within the CD cavity, based on the structure of the 1: 1 host-guest around state complexes and on the influence of the intracavity interactions on the reactive singlet excited state of 1-3. (c) 2005 Elsevier B.V. All rights reserved. (literal)

Prodotto di

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Studio delle interazioni legando-recettore in sistemi modello mediante metodi spettroscopici e fotofisici (LEGARE) (PM.P06.005.002) (Modulo)

Autore CNR

• ILSE GERT MANET (Unità di personale interno)
• FRANCESCO MANOLI (Persona)
• GIANCARLO MARCONI (Unità di personale interno)
• SANDRA MONTI (Persona)

Incoming links:

Prodotto

• Institute for organic syntheses and photoreactivity (ISOF) (Istituto)
• Studio delle interazioni legando-recettore in sistemi modello mediante metodi spettroscopici e fotofisici (LEGARE) (PM.P06.005.002) (Modulo)

Autore CNR di

• GIANCARLO MARCONI (Unità di personale interno)
• ILSE GERT MANET (Unità di personale interno)
• FRANCESCO MANOLI (Persona)
• SANDRA MONTI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of photochemistry and photobiology. A, Chemistry (Rivista)