An iron(II) diamine diketonate molecular complex: Synthesis, characterization and application in the CVD of Fe2O3 thin films (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• An iron(II) diamine diketonate molecular complex: Synthesis, characterization and application in the CVD of Fe2O3 thin films (Articolo in rivista) (literal)

Anno

• 2012-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.ica.2011.10.036 (literal)

Alternative label

• Barreca D.; Carraro G.; Gasparotto A.; MacCato C.; Seraglia R.; Tabacchi G. (2012)
  An iron(II) diamine diketonate molecular complex: Synthesis, characterization and application in the CVD of Fe2O3 thin films
  in Inorganica Chimica Acta (Testo stamp.)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Barreca D.; Carraro G.; Gasparotto A.; MacCato C.; Seraglia R.; Tabacchi G. (literal)

Pagina inizio

• 161 (literal)

Pagina fine

• 166 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni

• Invited Paper (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0020169311008541 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 38 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto

• pubblicazione scientifica (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1,5: CNR-ISTM and INSTM, Department of Chemistry, Padova University, 35131 Padova, Italy / 2,3,4: Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy / 6: Department of Chemical and Environmental Science, Insubria University and INSTM, 22100 Como, Italy (literal)

Titolo

• An iron(II) diamine diketonate molecular complex: Synthesis, characterization and application in the CVD of Fe2O3 thin films (literal)

Abstract

• The preparation of the second generation iron(II) complex Fe(hfa)2-TMEDA (hfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate, TMEDA = N,N,N,N'-tetramethylethylenediamine) is performed by reacting iron(II) chloride with Hhfa and TMEDA in two subsequent steps. Density functional theory data show that the compound possesses a distorted octahedral geometry, with the two beta-diketonate ligands in a cis configuration. The complex mass transport properties and fragmentation pattern are investigated by thermal analyses and electron impact mass spectrometry, respectively. In addition, its experimental and simulated IR spectra are presented. For the first time, Fe(hfa)2-TMEDA was successfully applied in the chemical vapor deposition (CVD) of iron oxide on Si(100). Structural, compositional and morphological analyses evidence the possibility of obtaining pure, single-phase and homogeneous beta-Fe2O3 films. (literal)

Prodotto di

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.001) (Modulo)

Autore CNR

• ROBERTA SERAGLIA (Persona)
• DAVIDE BARRECA (Persona)

Insieme di parole chiave

• Keywords of "An iron(II) diamine diketonate molecular complex: Synthesis, characterization and application in the CVD of Fe2O3 thin films" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.001) (Modulo)

Autore CNR di

• DAVIDE BARRECA (Persona)
• ROBERTA SERAGLIA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "An iron(II) diamine diketonate molecular complex: Synthesis, characterization and application in the CVD of Fe2O3 thin films" (Insieme di parole chiave)