http://www.cnr.it/ontology/cnr/individuo/prodotto/ID48662
beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process (Articolo in rivista)
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- beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process (Articolo in rivista) (literal)
- Anno
- 2012-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1039/c1dt11342a (literal)
- Alternative label
Barreca D.; Carraro G.; Devi A.; Fois, E.; Gasparotto G.; Seraglia R.; Maccato C.; Sada C.; Tabacchi G.; Tondello E.; Venzo A.; Winter M. (2012)
beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process
in Dalton transactions (2003. Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Barreca D.; Carraro G.; Devi A.; Fois, E.; Gasparotto G.; Seraglia R.; Maccato C.; Sada C.; Tabacchi G.; Tondello E.; Venzo A.; Winter M. (literal)
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- http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c1dt11342a#!divAbstract (literal)
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- pubblicazione scientifica (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1,6,11 : CNR-ISTM and INSTM, Department of Chemistry, Padova University, 35131 Padova, Italy /
2,5,7,10 : Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy /
3,12 : Inorganic Materials Chemistry Group, Lehrstuhl für Anorganische Chemie II, Ruhr-University Bochum, 44780 Bochum, Germany /
4,9 : Department of Chemical and Environmental Sciences, Insubria University and INSTM, 22100 Como, Italy /
8 : Department of Physics and CNISM, Padova University, 35131 Padova, Italy (literal)
- Titolo
- beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process (literal)
- Abstract
- Iron oxide is a key multi-functional material in many different fields of modern technology. The b-Fe2O3 cubic phase, one of the least studied FeO systems, was obtained by Chemical Vapor Deposition (CVD) using for the first time a Fe(II) b-diketonate diamine complex, Fe(hfa)2·TMEDA, as
the molecular source (hfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate; TMEDA = N,N,N¢,N¢-tetramethylethylenediamine). The strong visible light absorption of b-Fe2O3 deposits highlights their possible functional application in photocatalytic hydrogen production under solar light.
A comprehensive investigation on the Fe(II) complex, performed by a joint experimentaltheoretical approach, explains the molecular origin of its excellent thermal behaviour and reveals why this species
is a successful precursor for the CVD of iron oxide nanostructures (literal)
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