beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process (Articolo in rivista)

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  • beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process (Articolo in rivista) (literal)
Anno
  • 2012-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1039/c1dt11342a (literal)
Alternative label
  • Barreca D.; Carraro G.; Devi A.; Fois, E.; Gasparotto G.; Seraglia R.; Maccato C.; Sada C.; Tabacchi G.; Tondello E.; Venzo A.; Winter M. (2012)
    beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process
    in Dalton transactions (2003. Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Barreca D.; Carraro G.; Devi A.; Fois, E.; Gasparotto G.; Seraglia R.; Maccato C.; Sada C.; Tabacchi G.; Tondello E.; Venzo A.; Winter M. (literal)
Pagina inizio
  • 149 (literal)
Pagina fine
  • 155 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
  • http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c1dt11342a#!divAbstract (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 41 (literal)
Rivista
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  • pubblicazione scientifica (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • 1,6,11 : CNR-ISTM and INSTM, Department of Chemistry, Padova University, 35131 Padova, Italy / 2,5,7,10 : Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy / 3,12 : Inorganic Materials Chemistry Group, Lehrstuhl für Anorganische Chemie II, Ruhr-University Bochum, 44780 Bochum, Germany / 4,9 : Department of Chemical and Environmental Sciences, Insubria University and INSTM, 22100 Como, Italy / 8 : Department of Physics and CNISM, Padova University, 35131 Padova, Italy (literal)
Titolo
  • beta-Fe2O3 nanomaterials from an iron(II) diketonate-diamine complex: a study from molecular precursor to growth process (literal)
Abstract
  • Iron oxide is a key multi-functional material in many different fields of modern technology. The b-Fe2O3 cubic phase, one of the least studied Fe–O systems, was obtained by Chemical Vapor Deposition (CVD) using for the first time a Fe(II) b-diketonate diamine complex, Fe(hfa)2·TMEDA, as the molecular source (hfa = 1,1,1,5,5,5-hexafluoro-2,4-pentanedionate; TMEDA = N,N,N¢,N¢-tetramethylethylenediamine). The strong visible light absorption of b-Fe2O3 deposits highlights their possible functional application in photocatalytic hydrogen production under solar light. A comprehensive investigation on the Fe(II) complex, performed by a joint experimental–theoretical approach, explains the molecular origin of its excellent thermal behaviour and reveals why this species is a successful precursor for the CVD of iron oxide nanostructures (literal)
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