http://www.cnr.it/ontology/cnr/individuo/prodotto/ID48625
Structure and catalytic activity of hosted in mesoporous silicas copper species: effect of preparation procedure and support pore topology. (Articolo in rivista)
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- Structure and catalytic activity of hosted in mesoporous silicas copper species: effect of preparation procedure and support pore topology. (Articolo in rivista) (literal)
- Anno
- 2011-01-01T00:00:00+01:00 (literal)
- Alternative label
Tsoncheva, T.; Dal Santo, V.; Gallo, A.; Scotti, N.; Dimitrov, M.; Kovacheva, D. (2011)
Structure and catalytic activity of hosted in mesoporous silicas copper species: effect of preparation procedure and support pore topology.
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- Tsoncheva, T.; Dal Santo, V.; Gallo, A.; Scotti, N.; Dimitrov, M.; Kovacheva, D. (literal)
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- Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, 1113, Sofia, Bulgaria
Istituto di Scienze e Tecnologie Molecolari (ISTM-CNR), I-20133 Milano, Italy
Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev St., Block 13, 1113, Sofia, Bulgaria
Dept. CIMA L. Malatesta University of Milan, Via Venezian 21, 20133, Milano, Italy (literal)
- Titolo
- Structure and catalytic activity of hosted in mesoporous silicas copper species: effect of preparation procedure and support pore topology. (literal)
- Abstract
- Copper modifications of ordered mesoporous materials with different pore topology (SBA-15 and KIT-6) were prepared by incipient wetness impregnation and chemisorptionhydrolysis methods and further oxidative or consecutive oxidative/reductive treatment. The samples were characterized by nitrogen physisorption, XRD, XPS, FTIR, UVvis and TPRTG techniques. The ordered structures and the chemisorptionhydrolysis post synthetic method provide the formation of homogeneously dispersed in the mesopores copper species. The chemisorptionhydrolysis modification of the silicas with more opened 3D ordered structure (KIT-6) provides the formation of highly active catalysts, but their activity could be easily suppressed after the treatment under the reduction medium. (literal)
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