Epoxidation of methyl oleate with hydrogen peroxide. The use of Ti-containing silica solids as efficient heterogeneous catalysts (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Epoxidation of methyl oleate with hydrogen peroxide. The use of Ti-containing silica solids as efficient heterogeneous catalysts (Articolo in rivista) (literal)

Anno

• 2011-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1039/c1gc15151g (literal)

Alternative label

• Guidotti, Matteo; Gavrilova, Elena; Galarneau, Anne; Coq, Bernard; Psaro, Rinaldo; Ravasio, Nicoletta (2011)
  Epoxidation of methyl oleate with hydrogen peroxide. The use of Ti-containing silica solids as efficient heterogeneous catalysts
  in Green chemistry (Print); Royal Society of Chemistry, Cambridge (Regno Unito)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Guidotti, Matteo; Gavrilova, Elena; Galarneau, Anne; Coq, Bernard; Psaro, Rinaldo; Ravasio, Nicoletta (literal)

Pagina inizio

• 1806 (literal)

Pagina fine

• 1811 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 13 (literal)

Rivista

• Green chemistry (Rivista)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Scienze e Tecnologie Molecolari, Consiglio Nazionale delle Ricerche, via Golgi 19, I-20133 Milano, Italy Institut Charles Gerhardt Montpellier, UMR 5253 CNRS/UM2/ENSCM/UM1, ENSCM, 8 rue de l’Ecole Normale, 34296, Montpellier, France (literal)

Titolo

• Epoxidation of methyl oleate with hydrogen peroxide. The use of Ti-containing silica solids as efficient heterogeneous catalysts (literal)

Abstract

• Titanium-silica catalysts, obtained by grafting titanocene dichloride onto mesoporous silica (MCM-41 and MCM-48) and onto nanosized pyrogenic silica, were tested in the epoxidation of methyl oleate using aqueous hydrogen peroxide. All titanium-containing materials, combined with the slow addition of hydrogen peroxide, showed good catalytic activity and comparable behaviour in terms of conversion, selectivity and yield of methyl epoxystearate, notwithstanding the morphology and the texture of the silica support. By optimizing the reaction conditions (especially, the catalyst to substrate ratio), high yields up to 91% in epoxide were obtained for Ti/MCM-41 with a high stereoselectivity (80%) for the cis-epoxide. The formation of the cis/trans-epoxide and the nature of the catalytic reaction pathway are also discussed. (literal)

Editore

• Royal Society of Chemistry (Editore)

Prodotto di

• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• MARIA NICOLETTA RAVASIO (Persona)
• RINALDO PSARO (Unità di personale interno)
• MATTEO GUIDOTTI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Epoxidation of methyl oleate with hydrogen peroxide. The use of Ti-containing silica solids as efficient heterogeneous catalysts" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR di

• RINALDO PSARO (Unità di personale interno)
• MARIA NICOLETTA RAVASIO (Persona)
• MATTEO GUIDOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Green chemistry (Rivista)

Editore di

• Royal Society of Chemistry (Editore)

Insieme di parole chiave di

• Parole chiave di "Epoxidation of methyl oleate with hydrogen peroxide. The use of Ti-containing silica solids as efficient heterogeneous catalysts" (Insieme di parole chiave)