http://www.cnr.it/ontology/cnr/individuo/prodotto/ID48583
Design and Use of Nanostructured Single-Site Heterogeneous Catalysts for the Selective Transformation of Fine Chemicals (Articolo in rivista)
- Type
- Label
- Design and Use of Nanostructured Single-Site Heterogeneous Catalysts for the Selective Transformation of Fine Chemicals (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.3390/molecules15063829 (literal)
- Alternative label
Dal Santo, V.; Pirovano, C.; Liguori, F.; Guidotti, M. (2010)
Design and Use of Nanostructured Single-Site Heterogeneous Catalysts for the Selective Transformation of Fine Chemicals
in Molecules (Basel, Online); Molecular Diversity Preservation International-MDPI, Basel (Svizzera)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Dal Santo, V.; Pirovano, C.; Liguori, F.; Guidotti, M. (literal)
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- ISI Web of Science (WOS) (literal)
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- CNR ISTM Milano, I-20133 Milan, Italy.
ICCOM-CNR I-50019, Sesto Fiorentino (FI), Italy. (literal)
- Titolo
- Design and Use of Nanostructured Single-Site Heterogeneous Catalysts for the Selective Transformation of Fine Chemicals (literal)
- Abstract
- Nanostructured single-site heterogeneous catalysts possess the advantages of classical solid catalysts, in terms of easy recovery and recycling, together with a defined tailored chemical and steric environment around the catalytically active metal site. The use of inorganic oxide supports with selected shape and porosity at a nanometric level may have a relevant impact on the regio- and stereochemistry of the catalytic reaction.
Analogously, by choosing the optimal preparation techniques to obtain spatially isolated and well-characterised active sites, it is possible to achieve performances that are comparable to (or, in the most favourable cases, better than) those obtained with homogeneous systems. Such catalysts are therefore particularly suitable for the transformation of highly-functionalised fine chemicals and some relevant examples where
high chemo-, regio- and stereoselectivity are crucial will be described. (literal)
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