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Hafnium carbamates and ureates: new class of precursors for low-temperature growth of HfO2 thin films (Articolo in rivista)
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- Hafnium carbamates and ureates: new class of precursors for low-temperature growth of HfO2 thin films (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1039/b821128k (literal)
- Alternative label
a- Pothiraja, R.; a- Milanov, A. P.; b- Barreca, D.; c- Gasparotto, A.; d- Becker, H.-W.; a- Winter, M.; a- Fischer, R. A.; a- Devi, A. (2009)
Hafnium carbamates and ureates: new class of precursors for low-temperature growth of HfO2 thin films
in Chemical communications (Lond., 1996, Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- a- Pothiraja, R.; a- Milanov, A. P.; b- Barreca, D.; c- Gasparotto, A.; d- Becker, H.-W.; a- Winter, M.; a- Fischer, R. A.; a- Devi, A. (literal)
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- articolo con autori stranieri (literal)
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- http://pubs.rsc.org/en/Content/ArticleLanding/2009/CC/b821128k (literal)
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- DOI: 10.1039/b821128k (literal)
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- 1,2,6,7,8 : Lehrstuhl fur Anorganische Chemie II, Inorganic Materials Chemistry Group, Ruhr-University Bochum, D-44780 Bochum, Germany
3 : ISTM-CNR and INSTM, 35131 Padova, Italy
4 : Department of Chemistry, Padova University and INSTM, 35131 Padova, Italy
5 : Lehrstuhl fur Experimentalphysik III, Ruhr-University Bochum, D-44780 Bochum, Germany (literal)
- Titolo
- Hafnium carbamates and ureates: new class of precursors for low-temperature growth of HfO2 thin films (literal)
- Abstract
- Novel volatile compounds of hafnium, namely tetrakis-N,Odialkylcarbamato
hafnium(IV) [Hf(iPrNC(O)OiPr)4] (1) and
tetrakis-N,N,N'-trialkylureato hafnium(IV) [Hf(iPrNC(O)N-
(Me)Et)4] (2), have been synthesized through the simple insertion
reaction of isopropyl isocyanate into hafnium isopropoxide and
hafnium ethylmethylamide, respectively; based on the promising
thermal properties, compound 1 has been evaluated as a precursor
for metalorganic chemical vapor deposition (MOCVD) of
HfO2 thin films, which resulted in the growth of stoichiometric
and crystalline layers with a uniform morphology at temperature
as low as 250°C. (literal)
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