Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.apcata.2009.01.026 (literal)

Alternative label

• Deliy, I. V.; Simakova, I.L.; Ravasio, N.; Psaro, R. (2009)
  Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate
  in Applied catalysis. A, General (Print); Elsevier, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Deliy, I. V.; Simakova, I.L.; Ravasio, N.; Psaro, R. (literal)

Pagina inizio

• 170 (literal)

Pagina fine

• 177 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 357 (literal)

Rivista

• Applied catalysis. A, General (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Boreskov Institute of Catalysis, Russian Academy of Science, Novosibirsk, RUSSIA (literal)

Titolo

• Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate (literal)

Abstract

• Kinetic peculiarities of cis methyl oleate hydrogenation over Pd/C, Ru/C, Rh/C, Pt/C and Ir/C were studied. Liquid phase hydrogenation was carried out at temperature 298 T 373 K and under hydrogen pressure within 1–10 bar using n-octane as a solvent. GLC and FTIR techniques were employed to characterize the reaction products. The effects of the catalyst amount, cis methyl oleate concentration, reaction temperature, and hydrogen pressure on the rates of methyl oleate hydrogenation and cis-trans isomerization were investigated. A simple reaction scheme involving cis methyl oleate hydrogenation and cis-trans isomerization was proposed for kinetic modeling. A good agreement was obtained between the calculated kinetic curves and the experimental data for the isomerization and hydrogenation of methyl oleate. It was shown that the second-row metals (Ru, Rh, Pd) display high activity in isomerization whereas the third-row metals (Ir, Pt) exhibit minor activity. (literal)

Editore

• Elsevier (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR

• MARIA NICOLETTA RAVASIO (Persona)
• RINALDO PSARO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Processi chimici per la bioraffineria (PM.P03.004.002) (Modulo)

Autore CNR di

• RINALDO PSARO (Unità di personale interno)
• MARIA NICOLETTA RAVASIO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Applied catalysis. A, General (Rivista)

Editore di

• Elsevier (Editore)

Insieme di parole chiave di

• Keywords of "Catalytic behaviour of carbon supported platinum group metals in the hydrogenation and isomerization of methyl oleate" (Insieme di parole chiave)