Insight into the properties of Fe oxide present in high concentrations on mesoporous silica (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Insight into the properties of Fe oxide present in high concentrations on mesoporous silica (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jcat.2008.12.016 (literal)

Alternative label

• Gervasini, A.; Messi, C.; Carniti, P.; Ponti, A.; Ravasio, N.; Zaccheria, F. (2009)
  Insight into the properties of Fe oxide present in high concentrations on mesoporous silica
  in Journal of catalysis (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Gervasini, A.; Messi, C.; Carniti, P.; Ponti, A.; Ravasio, N.; Zaccheria, F. (literal)

Pagina inizio

• 224 (literal)

Pagina fine

• 234 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 262 (literal)

Rivista

• Journal of catalysis (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• CNR ISTM Dipartimento Chimica Fisica e Elettrochimica, Università di Milano, via C.Golgi 19, 20133 Milano (literal)

Titolo

• Insight into the properties of Fe oxide present in high concentrations on mesoporous silica (literal)

Abstract

• Oxide catalysts containing highly dispersed Fe phases supported on a mesoporous, high surface area silica, with iron in a wide range of concentration (4 < Fe2O3 mass% < 17), are presented. Although the samples have great variation of the iron loading, they maintained good Fe-dispersion and low metal aggregation, even those with the highest concentrations of iron. By increasing the Fe-loading, the DR–UV–vis spectra showed that the band centered at 360 nm (low nuclearity 2d-Fe oxo entities) became more intense, while the band at 500 nm (typical of 3d-Fe2O3 nanoparticles) remained of low intensity and quite constant. Formation of significant amount of isolated Fe3+ centers (band at ca. 230 nm) were also identified, in agreement with EPR evidences. The titrated amount of surface acid sites increased with the Fe loading, because of the increased amount of FeOx species, acting as Lewis acid sites. The test reaction of isomerization of ±-pinene oxide revealed the prominent presence of Lewis acid sites on all the samples with main formation of the ±-campholenic aldehyde product. The selectivity to ±-campholenic aldehyde was around 53% for all the catalysts, independent of the Fe-loading. However, productivity to ±-campholenic aldehyde increased with Fe concentration, because of the increase of reaction rates as higher the Fe content was. Active acid Fe-sites could be associated with isolated Fe centers and in particular with low nuclearity 2d-Fe oxo entities. (literal)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR

• MARIA NICOLETTA RAVASIO (Persona)
• Antonella Gervasini (Persona)
• FEDERICA ZACCHERIA (Unità di personale interno)
• ALESSANDRO PONTI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Insight into the properties of Fe oxide present in high concentrations on mesoporous silica" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR di

• FEDERICA ZACCHERIA (Unità di personale interno)
• MARIA NICOLETTA RAVASIO (Persona)
• ALESSANDRO PONTI (Unità di personale interno)
• Antonella Gervasini (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of catalysis (Rivista)

Insieme di parole chiave di

• Keywords of "Insight into the properties of Fe oxide present in high concentrations on mesoporous silica" (Insieme di parole chiave)