http://www.cnr.it/ontology/cnr/individuo/prodotto/ID48480
Highly stereoselective intramolecular a-arylation of self-stabilized non-racemic enolates: synthesis of a-quaternary a-amino acid derivatives. (Articolo in rivista)
- Type
- Label
- Highly stereoselective intramolecular a-arylation of self-stabilized non-racemic enolates: synthesis of a-quaternary a-amino acid derivatives. (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Alternative label
Lupi, Vittoria; Penso, Michele; Foschi, Francesca; Gassa, Federico; Mihali, Voichita; Tagliabue, Aaron. (2009)
Highly stereoselective intramolecular a-arylation of self-stabilized non-racemic enolates: synthesis of a-quaternary a-amino acid derivatives.
in Chemical communications (Lond., 1996, Print)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Lupi, Vittoria; Penso, Michele; Foschi, Francesca; Gassa, Federico; Mihali, Voichita; Tagliabue, Aaron. (literal)
- Pagina inizio
- Pagina fine
- Rivista
- Note
- ISI Web of Science (WOS) (literal)
- Titolo
- Highly stereoselective intramolecular a-arylation of self-stabilized non-racemic enolates: synthesis of a-quaternary a-amino acid derivatives. (literal)
- Abstract
- The one-pot stereoselective conversion of N-(4-nitrobenzene)sulfonyl-a-amino acid tert-Bu esters into the corresponding N-alkyl-a-(4-nitrophenyl)-a-amino esters has been realized through N-alkylation of the starting amido esters, followed by N-Ca migration of the p-nitrophenyl group and the loss of sulfur dioxide; the asym. induction is detd. by an intermediate non-racemic enolate, without the need of an external source of chirality.
(literal)
- Prodotto di
- Autore CNR
Incoming links:
- Prodotto
- Autore CNR di
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi