Application of Chiral Amine-Imine Ligands in Palladium-Catallyzed Polyketone Synthesis: Effect of Ligand Backbone on the Polymer Stereochemistry (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Application of Chiral Amine-Imine Ligands in Palladium-Catallyzed Polyketone Synthesis: Effect of Ligand Backbone on the Polymer Stereochemistry (Articolo in rivista) (literal)

Anno

• 2009-01-01T00:00:00+01:00 (literal)

Alternative label

• Axet, M.R.; Amoroso, F.; Bottari, G.; D'Amora, A.; Zangrando, E.; Faratone, F.; Drommi, D.; Saporita, M.; Carfagna, C.; Natanti, P.; Seraglia, R.; Milani, B. (2009)
  Application of Chiral Amine-Imine Ligands in Palladium-Catallyzed Polyketone Synthesis: Effect of Ligand Backbone on the Polymer Stereochemistry
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Axet, M.R.; Amoroso, F.; Bottari, G.; D'Amora, A.; Zangrando, E.; Faratone, F.; Drommi, D.; Saporita, M.; Carfagna, C.; Natanti, P.; Seraglia, R.; Milani, B. (literal)

Pagina inizio

• 4464 (literal)

Pagina fine

• 4474 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 28 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• DOI: 10.1021/om900300w (literal)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• Application of Chiral Amine-Imine Ligands in Palladium-Catallyzed Polyketone Synthesis: Effect of Ligand Backbone on the Polymer Stereochemistry (literal)

Abstract

• Two pairs of enantiomerically pure chiral bidentate nitrogen-donor ligands (N*-N) featuring one sp(3) and one sp(2) nitrogen atom have been applied to the CO/vinyl arene copolymerization reaction catalyzed by the corresponding monocationic palladium(11) complexes [Pd(CH3)(CH3CN)-(N*-N)][PF6]. The ligand frame containing the sp(2) nitrogen atom is a 2-pyridinyl or an 8-quinolinyl building block, while the chiral framework of the ligand derives from (S)-(+)-2.2'-(2-azapropane-1,3-diyl)-1,1'-binaphthalene or from trans-2.5-dimethylpyrrolidinyl. Ligands with the binaphthyl moiety generate catalysts showing a moderate activity, while ligands having the pyrrolidinyl fragment results in very low activity species. The stereochemistry of the synthesized polyketones depends of the sp(2) nitrogen-containing fragment: ligands with the 2-pyridinyl group lead to atactic copolymers, whereas those with the quinolinyl moiety give an isotactic polyketone. The effect of the nature of the quinone, added to the reaction mixture as oxidant, has been investigated MALDI-TOF analysis reveals the formation of several polymeric chains, differing in the presence of various end-groups. (literal)

Prodotto di

• Institute of molecular science and technologies (ISTM) (Istituto)
• Identificazione biomarcatori proteici per diabete, nefropatie e tumori mediante spettrometria di massa (PM.P06.008.001) (Modulo)

Autore CNR

• ROBERTA SERAGLIA (Persona)

Incoming links:

Prodotto

• Institute of molecular science and technologies (ISTM) (Istituto)
• Identificazione biomarcatori proteici per diabete, nefropatie e tumori mediante spettrometria di massa (PM.P06.008.001) (Modulo)

Autore CNR di

• ROBERTA SERAGLIA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)