Complexes of Al(III) with D-gluconic acid (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Complexes of Al(III) with D-gluconic acid (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.poly.2007.08.035 (literal)

Alternative label

• A. Lakatos; T. Kiss; R. Bertani; A. Venzo; V.B. Di Marco (2008)
  Complexes of Al(III) with D-gluconic acid
  in Polyhedron; Elsevier BV, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• A. Lakatos; T. Kiss; R. Bertani; A. Venzo; V.B. Di Marco (literal)

Pagina inizio

• 118 (literal)

Pagina fine

• 124 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.sciencedirect.com/science/article/pii/S0277538707005396 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 27 (literal)

Rivista

• Polyhedron (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-Bioinorganic Chemistry Research Group of the Hungarian Academy of Sciences, University of Szeged, P.O. Box 440, H-6701 Szeged, Hungary 2-Department of Inorganic and Analytical Chemistry, University of Szeged, P.O. Box 440, H-6701 Szeged, Hungary 3-Department of Chemical Processes and Engineering, Universita di Padova, Via Marzolo 9, 35131 Padova, Italy 4-CNR-ISTM, Institute of Sciences and Molecular Technologies, Via Marzolo 1, I-35131 Padova, Italy 5-Department of Chemical Sciences, University of Padova, Via Marzolo 1, 35131 Padova, Italy (literal)

Titolo

• Complexes of Al(III) with D-gluconic acid (literal)

Abstract

• The complexation of Al(III) withD-gluconic acid was studied in solution by means of pH-potentiometry, ESI mass spectrometry and one- and two-dimensional NMR spectroscopy. Six complexes were found to form in solution from pH 2 to 10: [AlL]2+, [AlLH-1]+, [AlLH-2], [AlLH-3]-, [AlL2H11] and [AlL2H-2]-. NMR spectroscopy indicated very complicated chemical exchange processes between the free ligand and gluconic acid molecules bound in the metal complexes, with different coordination modes resulting in changes both of the chemical shift and of the line shape of the signals. A solid complex [AlL2H-1].2(H2O) was isolated as a microcrystalline powder and characterized. The structures of the complexes are discussed on the basis of the spectroscopic results and MM force field calculations. (literal)

Editore

• Elsevier BV (Editore)

Prodotto di

• Sistemi molecolari e prodotti funzionali (PM.P03.010.001) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• ALFONSO VENZO (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "Complexes of Al(III) with D-gluconic acid" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Sistemi molecolari e prodotti funzionali (PM.P03.010.001) (Modulo)

Autore CNR di

• ALFONSO VENZO (Unità di personale interno)

Editore di

• Elsevier BV (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polyhedron (Rivista)

Insieme di parole chiave di

• Parole chiave di "Complexes of Al(III) with D-gluconic acid" (Insieme di parole chiave)