Surface functionalization with phosphazenes: Part 6. Modification of polyethylene-Co-polyvinylalcohol copolymer surface plates with fluorinated alcohols and azobenzene derivatives using chlorinated phosphazenes as coupling agents (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Surface functionalization with phosphazenes: Part 6. Modification of polyethylene-Co-polyvinylalcohol copolymer surface plates with fluorinated alcohols and azobenzene derivatives using chlorinated phosphazenes as coupling agents (Articolo in rivista) (literal)

Anno

• 2008-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1007/s10904-008-9209-9 (literal)

Alternative label

• Milani, R.; Gleria, M.; Gross, S.; De Jaeger, R.; Mazzah, A.; Gengembre, L.; Frere, M.; Jama, C. (2008)
  Surface functionalization with phosphazenes: Part 6. Modification of polyethylene-Co-polyvinylalcohol copolymer surface plates with fluorinated alcohols and azobenzene derivatives using chlorinated phosphazenes as coupling agents
  in Journal of inorganic and organometallic polymers and materials (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Milani, R.; Gleria, M.; Gross, S.; De Jaeger, R.; Mazzah, A.; Gengembre, L.; Frere, M.; Jama, C. (literal)

Pagina inizio

• 344 (literal)

Pagina fine

• 351 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 18 (literal)

Rivista

• Journal of inorganic and organometallic polymers and materials (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 18 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 3 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• [De Jaeger, Roger; Mazzah, Ahmed] USTL, CNRS, UMR 8516, LASIR, F-59655 Villeneuve Dascq, France. [Milani, Roberto] Univ Padua, Dipartimento Sci Chim, I-35131 Padua, Italy. [Gleria, Mario; Gross, Silvia] Univ Padua, CNR, Dipartimento Proc Chim Ingn, ISTM,Sez Padova, I-35131 Padua, Italy. [Gengembre, Leon; Frere, Martine] USTL, CNRS, UMR 8181, UCCS, F-59655 Villeneuve Dascq, France. [Jama, Charafeddine] ENSCL, UMR 8008, LSPES, Lab PERF, F-59652 Villeneuve Dascq, France. (literal)

Titolo

• Surface functionalization with phosphazenes: Part 6. Modification of polyethylene-Co-polyvinylalcohol copolymer surface plates with fluorinated alcohols and azobenzene derivatives using chlorinated phosphazenes as coupling agents (literal)

Abstract

• In this paper we describe a two-step surface modification process of poly(ethylene-co-vinyl alcohol) by exploiting hexachlorocyclophosphazene and poly(dichlorophosphazene) as coupling agents. Part of the P-Cl groups of the chlorophosphazenes is first reacted with the surface hydroxylic groups of the substrate to form covalent P-O-C bonds, the remaining being utilized for successive substitution reactions with different nucleophiles (i.e. 2,2,2-trifluoroethanol, heptadecafluorononanol and 4-hydroxyazobenzene). Modified surface properties, such as hydrophobicity improvement with fluorinated alcohols and photochromic features with the azobenzene derivative, were verified by contact angle measurements and UV-Vis spectroscopy, respectively, while changes in surface composition were demonstrated through XPS spectroscopy. (literal)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.001) (Modulo)
• Modeling computazionale di sistemi complessi costituiti da molecole interagenti con superfici e nanosistemi (PM.P07.006.001) (Modulo)

Autore CNR

• MARIO GLERIA (Persona)
• SILVIA GROSS (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Surface functionalization with phosphazenes: Part 6. Modification of polyethylene-Co-polyvinylalcohol copolymer surface plates with fluorinated alcohols and azobenzene derivatives using chlorinated phosphazenes as coupling agents" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Modeling computazionale di sistemi complessi costituiti da molecole interagenti con superfici e nanosistemi (PM.P07.006.001) (Modulo)
• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.001) (Modulo)

Autore CNR di

• SILVIA GROSS (Unità di personale interno)
• MARIO GLERIA (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of inorganic and organometallic polymers and materials (Rivista)

Insieme di parole chiave di

• Keywords of "Surface functionalization with phosphazenes: Part 6. Modification of polyethylene-Co-polyvinylalcohol copolymer surface plates with fluorinated alcohols and azobenzene derivatives using chlorinated phosphazenes as coupling agents" (Insieme di parole chiave)