Synthesis and Characterization of Osmium-Containing Silsesquioxanes: High-Yield Routes to {Os3(CO)10(mu-H)[(mu-O)Si7O10(c-C6H11)7]} and the New Clusters {Os3(CO)10(mu-H)[(mu-O)Si7O9(OH)2(c-C6H11)7]}, {[Os3(CO)10(mu-H)]2(mu-O)2Si7O9(OH)(c-C6H11)7}, {Os3(CO)10(mu-H)[(mu-O)Si8O11(OH)(c-C6H11)8]}, and {[Os3(CO)10(mu-H)]2(mu-O)2Si8O11(c-C6H11)8} (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Synthesis and Characterization of Osmium-Containing Silsesquioxanes: High-Yield Routes to {Os3(CO)10(mu-H)[(mu-O)Si7O10(c-C6H11)7]} and the New Clusters {Os3(CO)10(mu-H)[(mu-O)Si7O9(OH)2(c-C6H11)7]}, {[Os3(CO)10(mu-H)]2(mu-O)2Si7O9(OH)(c-C6H11)7}, {Os3(CO)10(mu-H)[(mu-O)Si8O11(OH)(c-C6H11)8]}, and {[Os3(CO)10(mu-H)]2(mu-O)2Si8O11(c-C6H11)8} (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/om060844c (literal)

Alternative label

• Lucenti, E.; Feher, F. J.; Ziller, J. W. (2007)
  Synthesis and Characterization of Osmium-Containing Silsesquioxanes: High-Yield Routes to {Os3(CO)10(mu-H)[(mu-O)Si7O10(c-C6H11)7]} and the New Clusters {Os3(CO)10(mu-H)[(mu-O)Si7O9(OH)2(c-C6H11)7]}, {[Os3(CO)10(mu-H)]2(mu-O)2Si7O9(OH)(c-C6H11)7}, {Os3(CO)10(mu-H)[(mu-O)Si8O11(OH)(c-C6H11)8]}, and {[Os3(CO)10(mu-H)]2(mu-O)2Si8O11(c-C6H11)8}
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Lucenti, E.; Feher, F. J.; Ziller, J. W. (literal)

Pagina inizio

• 75 (literal)

Pagina fine

• 82 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/om060844c (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 26 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 8 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Scienze e Tecnologie Molecolari del CNR, Via C. Golgi 19, 20133 Milano, Italy Department of Chemistry, UniVersity of California, IrVine, California 92697-2025 (literal)

Titolo

• Synthesis and Characterization of Osmium-Containing Silsesquioxanes: High-Yield Routes to {Os3(CO)10(mu-H)[(mu-O)Si7O10(c-C6H11)7]} and the New Clusters {Os3(CO)10(mu-H)[(mu-O)Si7O9(OH)2(c-C6H11)7]}, {[Os3(CO)10(mu-H)]2(mu-O)2Si7O9(OH)(c-C6H11)7}, {Os3(CO)10(mu-H)[(mu-O)Si8O11(OH)(c-C6H11)8]}, and {[Os3(CO)10(mu-H)]2(mu-O)2Si8O11(c-C6H11)8} (literal)

Abstract

• The reactions of [Os3(CO)10(mu-H)(mu-OH)] (3) with the incompletely condensed silsesquioxanes [(c- C6H11)7Si7O9(OH)3] (1) and [(c-C6H11)8Si8O11(OH)2] (2) afford in high yield {Os3(CO)10(mu-H)[(mu-O)- Si7O10(c-C6H11)7]} (4) and the new compounds {Os3(CO)10(mu-H)[(mu-O)Si7O9(OH)2(c-C6H11)7]} (5), {[Os3(CO)10(mu-H)]2(mu-O)2Si7O9(OH)(c-C6H11)7} (6), {Os3(CO)10(mu-H)[(mu-O)Si8O11(OH)(c-C6H11)8]} (8), and {[Os3(CO)10(mu-H)]2(mu-O)2Si8O11(c-C6H11)8} (9), which are discrete molecular models of silica-anchored [Os3(CO)10(mu-H)(mu-OSi)]. Compounds 6 and 9 represent the first examples of complexes containing two [Os3(CO)10(mu-H)] cluster cores. The X-ray structures of 5, 8, and 9 are reported. (literal)

Prodotto di

• Nuovi materiali per produzione e 'storage' di idrogeno (PM.P03.005.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• ELENA LUCENTI (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Nuovi materiali per produzione e 'storage' di idrogeno (PM.P03.005.002) (Modulo)

Autore CNR di

• ELENA LUCENTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)