http://www.cnr.it/ontology/cnr/individuo/prodotto/ID48208
Electropolymerizable terthiophene S,S-dioxide-fullerene Diels-Alder adduct for donor/acceptor double-cable polymers (Articolo in rivista)
- Type
- Label
- Electropolymerizable terthiophene S,S-dioxide-fullerene Diels-Alder adduct for donor/acceptor double-cable polymers (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/marc.200700174 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Vida Y.; Suau R.; Casado J.; Berlin A.; Lopez Navarrete J.T.; Perez-Inestrosa E. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://onlinelibrary.wiley.com (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- CNR-ISTM; Department of Organic Chemistry, University of Malaga; , Department of Physical Chemistry, University of Malaga (literal)
- Titolo
- Electropolymerizable terthiophene S,S-dioxide-fullerene Diels-Alder adduct for donor/acceptor double-cable polymers (literal)
- Abstract
- The preparation of a novel fullerene-thiophene derivative by Diels-Alder addition of terthiophene
S,S-dioxide was demonstrated. Extrusion of SO2 from the adduct is an effective process
that yields a stable cyclohexadiene-1,4-bisthiophene-C60 adduct in good isolable yield. The
product has been accurately characterized and opens the way to synthesize new C60 derivatives
''via'' Diels-Alder methodology without the possibility of cycloreversion. Electrochemical
and spectroscopic properties of this macromolecule
were studied and supported by theoretical
calculations to interpret its electronic structure.
The first approach to the electropolymerization
of this macromonomer produces donoracceptor
molecular wires providing a new
and versatile way to fullerene-based double
cable polymers. (literal)
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- Autore CNR
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