http://www.cnr.it/ontology/cnr/individuo/prodotto/ID47916
Au/TiO2 nanosystems: a combined RF-Sputtering/Sol-Gel approach (Articolo in rivista)
- Type
- Label
- Au/TiO2 nanosystems: a combined RF-Sputtering/Sol-Gel approach (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1021/cm0353308 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Armelao L; Barreca D; Bottaro G; Gasparotto A; Tondello E; Ferroni M; Polizzi S (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url
- http://pubs.acs.org/doi/abs/10.1021/cm0353308 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- 1-3 : ISTM-CNR and INSTM, Department of Chemistry, Padova University, Via Marzolo, 1, 35131 Padova, Italy /
4-5 : Department of Chemistry, Padova University and INSTM, Via Marzolo, 1, 35131 Padova, Italy /
6 : Phys. Chemistry Department and INFM, UdR Venezia, Ca' Foscari Venice University, Via Torino, 155/B, Venezia-Mestre, Italy /
7 : Physical Chemistry Department, Ca' Foscari Venice University, Via Torino, 155/B, Venezia-Mestre, Italy (literal)
- Titolo
- Au/TiO2 nanosystems: a combined RF-Sputtering/Sol-Gel approach (literal)
- Abstract
- An original synthetic approach to Au/TiO2 nanosystems is developed. The adopted technique is based on the RF-sputtering of gold (guest) on porous titania xerogels (host) obtained by the sol-gel route. Such a combined synthetic pathway joins the peculiarities offered by the features of the sol-gel layers (porosity, nonbridging groups) and the advantages of plasmochemical methods (conformal coverage, infiltration power). In particular, host titania substrates were first prepared on silica by dip-coating from ethanolic solutions of Ti(OPri)(4) (OPri=iso-propoxy) and Hacac (2,4-pentanedione). Subsequently, Au depositions were performed on the as-prepared xerogels in Ar plasmas at low temperatures. The resulting samples were finally annealed in air between 200 and 600 degreesC with the aim of tailoring the system features as a function of thermal treatment and gold content. Their structural, compositional, and morphological evolution was investigated by Glancing Incidence X-ray Diffraction (GIXRD), Transmission Electron Microscopy (TEM), optical absorption spectroscopy, X-ray Photoelectron Spectroscopy (XPS), and Atomic Force Microscopy (AFM). The adopted strategy enabled the synthesis of Au/TiO2 nanosystems with characteristics strongly dependent on the deposited gold amount and processing conditions. In this way, materials with tunable structure, composition, and optical properties could be synthesized. (literal)
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- Autore CNR
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