Thiophenolate clusters as potential nanosized building blocks for zinc-based nanocomposite materials: synthesis and characterization (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Thiophenolate clusters as potential nanosized building blocks for zinc-based nanocomposite materials: synthesis and characterization (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.ica.2005.03.011 (literal)

Alternative label

• 1-Pandolfo L.; 2-Seraglia R.; 2-Venzo A.; 2-Gross S.; 3-Kickelbick G. (2005)
  Thiophenolate clusters as potential nanosized building blocks for zinc-based nanocomposite materials: synthesis and characterization
  in Inorganica Chimica Acta (Testo stamp.); Elsevier BV, Amsterdam (Paesi Bassi)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• 1-Pandolfo L.; 2-Seraglia R.; 2-Venzo A.; 2-Gross S.; 3-Kickelbick G. (literal)

Pagina inizio

• 2739 (literal)

Pagina fine

• 2748 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://www.elsevier.com/locate/ica (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 358 (literal)

Rivista

• Inorganica Chimica Acta (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 10 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• 1-Depament of Chemical Sciences, University of Padova, Via Marzolo, 1, Padova I-35131, Italy 2-CNR - ISTM, University of Padova, via Marzolo, 1, Padova, Italy 3-Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9/165, 1060 Vienna, Austria (literal)

Titolo

• Thiophenolate clusters as potential nanosized building blocks for zinc-based nanocomposite materials: synthesis and characterization (literal)

Abstract

• The synthesis, the spectroscopic and structural characterization of different thiophenolate-capped zinc clusters are reported and described. In particular, different reactions of 4-chlorobenzenethiol with zinc salts yield the clusters [Me4N][Et3NH][Zn4(mu-S-C6H4-Cl)6(S-C6H4-Cl)4] 2a), [Et3NH]2[Zn4(mu-S-C6H4-Cl)6(S-C6H4-Cl)4] (2b), and [Me4N]2[Zn4(mu-S-C6H4-Cl)6(S-C6H4-Cl)4] (2c ), and also the thiophenolate derivative [Et3NH]2[Zn4(mu-S-C6H5)6(S-C6H5)4] (1b) was obtained. The nanosized thiophenolate-capped clusters were investigated by 1H and 13C NMR, elemental analysis, and electrospray ion-ization (ESI) mass spectrometry. NMR experiments provided insights into the dynamic behaviour of the clusters. The thermal decomposition patterns of 2c were analyzed in air as well as in nitrogen, indicating the formation of zinc oxide and metallic zinc, respectively. The X-ray structure of 2a revealed that the cluster core consists of an adamantane-like framework analogous to those realized in many other M4(SR)10 metal complexes (literal)

Editore

• Elsevier BV (Editore)

Prodotto di

• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.001) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)

Autore CNR

• ROBERTA SERAGLIA (Persona)
• SILVIA GROSS (Unità di personale interno)
• ALFONSO VENZO (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Thiophenolate clusters as potential nanosized building blocks for zinc-based nanocomposite materials: synthesis and characterization" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Progettazione molecolare di nanosistemi organizzati (PM.P05.007.001) (Modulo)

Autore CNR di

• SILVIA GROSS (Unità di personale interno)
• ROBERTA SERAGLIA (Persona)
• ALFONSO VENZO (Unità di personale interno)

Editore di

• Elsevier BV (Editore)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganica Chimica Acta (Rivista)

Insieme di parole chiave di

• Keywords of "Thiophenolate clusters as potential nanosized building blocks for zinc-based nanocomposite materials: synthesis and characterization" (Insieme di parole chiave)