Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability (Articolo in rivista) (literal)

Anno

• 2005-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.jcat.2004.12.021 (literal)

Alternative label

• Guidotti M.; Canaff C.; Coustard J.M.; Magnoux P.; Guisnet M. (2005)
  Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability
  in Journal of catalysis (Print); Academic Press, San Diego (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Guidotti M.; Canaff C.; Coustard J.M.; Magnoux P.; Guisnet M. (literal)

Pagina inizio

• 375 (literal)

Pagina fine

• 383 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 230 (literal)

Rivista

• Journal of catalysis (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 9 (literal)

Note

• Scopu (literal)
• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• a Faculté des Sciences Fondamentales et Appliquées, Université de Poitiers, UMR CNRS 6503, 40 av. du Recteur Pineau, 86022 Poitiers cedex, France b Faculté des Sciences Fondamentales et Appliquées, Université de Poitiers, UMR CNRS 6514, 40 av. du Recteur Pineau, 86022 Poitiers cedex, France c CNR - Istituto di Scienze e Tecnologie Molecolari, via Venezian 21, 20133 Milano, Italy (literal)

Titolo

• Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability (literal)

Abstract

• The acylation with acetic anhydride of six aromatic substrates with different features (degree of activation of the aromatic ring towards electrophilic substitution, number of rings, i.e., 1 or 2) was carried out in a batch reactor at 373 K over a H-BEA zeolite (Si/Al = 15) with nitrobenzene as a solvent. The acetylation rate was found to be very dependent on the degree of ring activation, with diffusion limitations playing only a limited role. The decrease of the rate with reaction time, which was very pronounced with poorly activated and deactivated substrates, is mainly due to the inhibiting effect of acetic acid and of the products of acetic anhydride condensation. (literal)

Editore

• Academic Press (Editore)

Prodotto di

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR

• MATTEO GUIDOTTI (Unità di personale interno)

Insieme di parole chiave

• Keywords of "Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Catalizzatori per la produzione chemo-, regio- e stereoselettiva di fine chemicals (PM.P03.002.002) (Modulo)

Autore CNR di

• MATTEO GUIDOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of catalysis (Rivista)

Editore di

• Academic Press (Editore)

Insieme di parole chiave di

• Keywords of "Acetylation of aromatic compounds over H-BEA zeolite: the influence of the substituents on the reactivity and on the catalyst stability" (Insieme di parole chiave)