Kinetic peculiarities of cis/trans methyl oleate formation during hydrogenation of methyl linoleate over Pd/MgO (Articolo in rivista)

Type
Label
  • Kinetic peculiarities of cis/trans methyl oleate formation during hydrogenation of methyl linoleate over Pd/MgO (Articolo in rivista) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.apcata.2004.10.017 (literal)
Alternative label
  • Deliy I.V., Maksimchuk N.M., Psaro R., Ravasio N., Dal Santo V., Recchia S., Paukshtis E.A., Golovin A.V., Semikolenov V.A. (2005)
    Kinetic peculiarities of cis/trans methyl oleate formation during hydrogenation of methyl linoleate over Pd/MgO
    in Applied catalysis. A, General (Print); Elsevier, Amsterdam (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Deliy I.V., Maksimchuk N.M., Psaro R., Ravasio N., Dal Santo V., Recchia S., Paukshtis E.A., Golovin A.V., Semikolenov V.A. (literal)
Pagina inizio
  • 99 (literal)
Pagina fine
  • 107 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 279 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Deliy I.V.;Maksimchuk N.M.; Paukshtis E.A.; Golovin A.V.; Semikolenov V.A. Boreskov Inst Catalysis, Novosibirsk 630090, Russia Recchia S. Univ Insubria Sede Como, Dipartimento Sci Chim Fis & Matemat, I-22100 Como, Italy (literal)
Titolo
  • Kinetic peculiarities of cis/trans methyl oleate formation during hydrogenation of methyl linoleate over Pd/MgO (literal)
Abstract
  • Kinetic peculiarities of cis and trans methyl oleate formation in the course of methyl linoleate hydrogenation over Pd/MgO were, studied. Liquid phase hydrogenation was carried out in temperature range of 303-323 K and under hydrogen pressure within 1-10 bar. Gas-liquid chromatography, IR and C-13 NMR techniques were employed to characterize the reaction products. Effects of hydrogen pressure. and re-action temperature on cis and trans methyl oleate. formation were studied. The General kinetic scheme and reaction mechanism of methyl linoleate hydrogenation and cis-trans methyl oleate isomerization have been proposed. (literal)
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