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Synthesis and characterization of zinc bis(O-isopropylxanthate) as single-source chemical vapor deposition precursor for ZnS (Articolo in rivista)

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Synthesis and characterization of zinc bis(O-isopropylxanthate) as single-source chemical vapor deposition precursor for ZnS (Articolo in rivista) (literal)

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1-Barreca D.; 2-Gasparotto A.; 2-Maragno C.; 1-Seraglia R.; 2-Tondello E.; 1-Venzo A.; 3-Krishnan V.; 3-Bertagnolli H. (2005)
Synthesis and characterization of zinc bis(O-isopropylxanthate) as single-source chemical vapor deposition precursor for ZnS
in Applied organometallic chemistry; John Wiley & Sons, Ltd., New York (Stati Uniti d'America)
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1-Barreca D.; 2-Gasparotto A.; 2-Maragno C.; 1-Seraglia R.; 2-Tondello E.; 1-Venzo A.; 3-Krishnan V.; 3-Bertagnolli H. (literal)

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1-ISTM-CNR, Department of Chemical Sciences, Padova University, Via Marzolo, 1, 35131 Padua, Italy 2-Department of Chemical Sciences , Padova University and INSTM, Via Marzolo, 1, 35131 Pad ua, I taly 3-Institut für Physikalische Chemie, Universitat Stuttgart, Pfaffenwalding, 55, 70569 Stuttgart, Germany (literal)

Titolo

Synthesis and characterization of zinc bis(O-isopropylxanthate) as single-source chemical vapor deposition precursor for ZnS (literal)

Abstract

The utilization of single-source molecular precursors in chemical vapor deposition (CVD) experiments requires a deep knowledge of their chemico-physical properties, with particular regard to thermal stability and fragmentation pattern. This study describes the synthesis and characterization of zinc bis(O-isopropylxanthate), Zn(O-iPrXan)2, [O-iPrXan = (CH3)2CHOCS2], a single-source precursor for the CVD of zinc(II)sulfide thin films and nanorods. Several analytical methods yielding complementary information (extended X-ray absorption fine structure, Raman, FT-IR, UV-Vis optical absorption, 1H and 13C NMR, thermogravimetric analysis, differential scanning calorimetry as well as mass spectrometry techniques, i.e. electrospray and electron ionization, mass-analyzed ion kinetic energy) are adopted for a comprehensive investigation of purity, structure, thermal behavior and decomposition pathways of the molecule. The most significant results are discussed critically and the properties useful for CVD applications are highlighted. (literal)

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