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Cadmium O-alkylxanthates as CVD precursors of CdS: a chemical characterization (Articolo in rivista)

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Cadmium O-alkylxanthates as CVD precursors of CdS: a chemical characterization (Articolo in rivista) (literal)

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1-Barreca D.; 2-Gasparotto A.; 2-Maragno C.; 1-Seraglia R.; 2-Tondello E.; 1-Venzo A.; 3-Krishnan V.; 3-Bertagnolli H. (2005)
Cadmium O-alkylxanthates as CVD precursors of CdS: a chemical characterization
in Applied organometallic chemistry; John Wiley & Sons, Ltd., New York (Stati Uniti d'America)
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1-Barreca D.; 2-Gasparotto A.; 2-Maragno C.; 1-Seraglia R.; 2-Tondello E.; 1-Venzo A.; 3-Krishnan V.; 3-Bertagnolli H. (literal)

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1-CNR-ISTN, Department of Chemical Sciences, Padova University, Via Marzolo, 1-35131 Padova, Italy 2-Department of Chemical Sciences , Padova University and INSTM, Via Marzolo, 1-35131 Padova , Italy 3-Institut für Physikalische C hemie, Universitat Stuttgart, Pfaffenwalding 55, D-70569 Stuttgart, Germany (literal)

Titolo

Cadmium O-alkylxanthates as CVD precursors of CdS: a chemical characterization (literal)

Abstract

Cadmium bis(O-alkylxanthates) are po tential single-source molecular precursors for the chemical vapor deposition (CVD) of Cd(II) sulfide thin films. In this work, a multi-technique characterization of Cd(O-RXan)2 compounds [where O-RXan is CH3CH2OCS2 (O-EtXan) or (CH3)2CHOCS2 (O-iPrXan)] is performed by means of several analytical methods (extended x-ray absorption fine structure, Raman, Fourier transform infrared and optical absorption, spectroscopics 1H and 13C NMR, thermal analysis and mass spectrometry) for a thorough investigation of their structure and chemical-physical properties. The most important results concerning the chemical behavior under different experimental conditions, with particular attention to relevant properties for CVD applications, are presented and discussed (literal)

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