http://www.cnr.it/ontology/cnr/individuo/prodotto/ID47529
Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA (Articolo in rivista)
- Type
- Label
- Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/S0022-3093(03)00196-0 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Gross S., Di Noto V., Schubert U. (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Univ Padua, CNR, ISTM, Padua, Italy
Univ Padua, Dept Inorgan Met Organ & Analyt Chem, Padua, Italy
Vienna Univ Technol, Inst Mat Chem, Vienna, Austria (literal)
- Titolo
- Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA (literal)
- Abstract
- Through photocopolymerisation of the cluster Zr4O2(OMc)(12) bearing 12 polymerisable groups with methylmethacrylate in a monomer:cluster molar ratio of 50, a novel inorganic-organic hybrid thin film was obtained. The prepared thin film, having a thickness of about 70 mum, was characterised through dielectric spectroscopy. The dielectric spectra of the film were measured at different temperatures (20-73.4 degreesC) and in the frequency range 20 Hz-1 MHz. The alpha and beta relaxations typical of polyalkylmethacrylate polymers were detected and the electric response mechanisms were investigated by analysing the dielectric spectra in terms of the Davidson-Cole phenomenological equation. Finally, a dielectric constant of 1.93 at 25 degreesC and 1 kHz was determined. This value classifies this system as a promising dielectric material for the development of electronic devices, such as polymer based field effect transistors. (literal)
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