Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA (Articolo in rivista)

Type
Label
  • Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/S0022-3093(03)00196-0 (literal)
Alternative label
  • Gross S., Di Noto V., Schubert U. (2003)
    Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA
    in Journal of non-crystalline solids
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Gross S., Di Noto V., Schubert U. (literal)
Pagina inizio
  • 154 (literal)
Pagina fine
  • 159 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 322 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 6 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo
  • 1-3 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Univ Padua, CNR, ISTM, Padua, Italy Univ Padua, Dept Inorgan Met Organ & Analyt Chem, Padua, Italy Vienna Univ Technol, Inst Mat Chem, Vienna, Austria (literal)
Titolo
  • Dielectric Investigation of Inorganic-Organic Hybrid Film Based on Zirconium Oxocluster-Crosslinked PMMA (literal)
Abstract
  • Through photocopolymerisation of the cluster Zr4O2(OMc)(12) bearing 12 polymerisable groups with methylmethacrylate in a monomer:cluster molar ratio of 50, a novel inorganic-organic hybrid thin film was obtained. The prepared thin film, having a thickness of about 70 mum, was characterised through dielectric spectroscopy. The dielectric spectra of the film were measured at different temperatures (20-73.4 degreesC) and in the frequency range 20 Hz-1 MHz. The alpha and beta relaxations typical of polyalkylmethacrylate polymers were detected and the electric response mechanisms were investigated by analysing the dielectric spectra in terms of the Davidson-Cole phenomenological equation. Finally, a dielectric constant of 1.93 at 25 degreesC and 1 kHz was determined. This value classifies this system as a promising dielectric material for the development of electronic devices, such as polymer based field effect transistors. (literal)
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