Solubility of 5-nitro- and 3-nitrosalicylic acids in an acetic acid/nitric acid mixture (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Solubility of 5-nitro- and 3-nitrosalicylic acids in an acetic acid/nitric acid mixture (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Alternative label

• Andreozzi, R; Canterino, M; Caprio, V; Di Somma, I; Sanchirico, R (2007)
  Solubility of 5-nitro- and 3-nitrosalicylic acids in an acetic acid/nitric acid mixture
  in Journal of chemical and engineering data
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Andreozzi, R; Canterino, M; Caprio, V; Di Somma, I; Sanchirico, R (literal)

Pagina inizio

• 122 (literal)

Pagina fine

• 125 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 52 (literal)

Rivista

• Journal of chemical and engineering data (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 1 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Università di Napoli Federico II Dipartimento di Ingegneria Chimica (literal)

Titolo

• Solubility of 5-nitro- and 3-nitrosalicylic acids in an acetic acid/nitric acid mixture (literal)

Abstract

• To better understand the batch production of 5-nitrosalicylic acid by means of the nitration of salicylic acid through the mixture nitric acid/acetic acid, the solubility of the two main mononitro derivatives of salicylic acid is investigated. For this purpose, the behavior of the two mononitro compounds in the ternary system organic/ acetic acid/nitric acid is separately studied at different temperatures (288 to 303) K and nitric acid concentrations [(0 to 2) molâL-1 for 5-nitrosalicylic acid, (0 to 1) molâL-1 for 3-nitrosalicylic acid]. The solubility of these compounds increases with a rise in temperature, whereas only the solubility of 5-nitrosalicylic acid is dependent upon the nitric acid concentration. The mutual effect of each organic acid on the solubility of the other is also investigated. The observed dependencies are explained through simple thermodynamic relationships. (literal)

Prodotto di

• Studio dei processi e tecnologie di combustione a basso impatto ambientale (ET.P01.003.001) (Modulo)
• Institute for research on combustion (IRC) (Istituto)

Autore CNR

• ROBERTO SANCHIRICO (Unità di personale interno)

Incoming links:

Prodotto

• Institute for research on combustion (IRC) (Istituto)
• Studio dei processi e tecnologie di combustione a basso impatto ambientale (ET.P01.003.001) (Modulo)

Autore CNR di

• ROBERTO SANCHIRICO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Journal of chemical and engineering data (Rivista)