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Does the entropy and volume dependence of the structural alpha-relaxation originate from the JohariGoldstein beta-relaxation? (Articolo in rivista)
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- Label
- Does the entropy and volume dependence of the structural alpha-relaxation originate from the JohariGoldstein beta-relaxation? (Articolo in rivista) (literal)
- Anno
- 2009-01-01T00:00:00+01:00 (literal)
- Alternative label
Prevosto, D.; Capaccioli, S.; Lucchesi, M.; Rolla, P.A.; Ngai, K.L. (2009)
Does the entropy and volume dependence of the structural alpha-relaxation originate from the JohariGoldstein beta-relaxation?
in Journal of non-crystalline solids
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Prevosto, D.; Capaccioli, S.; Lucchesi, M.; Rolla, P.A.; Ngai, K.L. (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- INFM-CNR Polylab, Largo B. Pontecorvo 3, I-56127 Pisa, Italy
Physics Department, University of Pisa, Largo B. Pontecorvo 3, I-56127 Pisa, Italy
Naval Research Laboratory, WA 20375-5320, USA (literal)
- Titolo
- Does the entropy and volume dependence of the structural alpha-relaxation originate from the JohariGoldstein beta-relaxation? (literal)
- Abstract
- Conventional theories of glass transition are focussed on reproducing the thermodynamic and dynamic
properties of the structural a-process. However, in the last decade a class of secondary relaxations, called
the JohariGoldstein (JG) b-relaxations, has attracted attention in view of the existence of various correlations
and similarities of its properties with the structural a-process. These experimental evidences suggest
that the secondary process may play a fundamental role in glass transition, and any theory of glass
transition would be incomplete until the inter-relations between the JG b-relaxation and the structural
relaxation have been considered. In this paper, some significant experimental results showing several
general and nontrivial connections between structural relaxation and JG b-relaxation are reported. In particular,
these connections indicate that, like the structural relaxation, the JG b-relaxation is entropy and
volume dependent. The experimental facts are consistent with the results of the coupling model. (literal)
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