Does the entropy and volume dependence of the structural alpha-relaxation originate from the Johari–Goldstein beta-relaxation? (Articolo in rivista)

Type
Label
  • Does the entropy and volume dependence of the structural alpha-relaxation originate from the Johari–Goldstein beta-relaxation? (Articolo in rivista) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Alternative label
  • Prevosto, D.; Capaccioli, S.; Lucchesi, M.; Rolla, P.A.; Ngai, K.L. (2009)
    Does the entropy and volume dependence of the structural alpha-relaxation originate from the Johari–Goldstein beta-relaxation?
    in Journal of non-crystalline solids
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Prevosto, D.; Capaccioli, S.; Lucchesi, M.; Rolla, P.A.; Ngai, K.L. (literal)
Pagina inizio
  • 705 (literal)
Pagina fine
  • 711 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 355 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • INFM-CNR Polylab, Largo B. Pontecorvo 3, I-56127 Pisa, Italy Physics Department, University of Pisa, Largo B. Pontecorvo 3, I-56127 Pisa, Italy Naval Research Laboratory, WA 20375-5320, USA (literal)
Titolo
  • Does the entropy and volume dependence of the structural alpha-relaxation originate from the Johari–Goldstein beta-relaxation? (literal)
Abstract
  • Conventional theories of glass transition are focussed on reproducing the thermodynamic and dynamic properties of the structural a-process. However, in the last decade a class of secondary relaxations, called the Johari–Goldstein (JG) b-relaxations, has attracted attention in view of the existence of various correlations and similarities of its properties with the structural a-process. These experimental evidences suggest that the secondary process may play a fundamental role in glass transition, and any theory of glass transition would be incomplete until the inter-relations between the JG b-relaxation and the structural relaxation have been considered. In this paper, some significant experimental results showing several general and nontrivial connections between structural relaxation and JG b-relaxation are reported. In particular, these connections indicate that, like the structural relaxation, the JG b-relaxation is entropy and volume dependent. The experimental facts are consistent with the results of the coupling model. (literal)
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