Scaling of local density correlations in a fluid close to freezing (Articolo in rivista)

Type
Label
  • Scaling of local density correlations in a fluid close to freezing (Articolo in rivista) (literal)
Anno
  • 2001-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1063/1.1406528 (literal)
Alternative label
  • Saija, F; Prestipino, S; Giaquinta, PV (2001)
    Scaling of local density correlations in a fluid close to freezing
    in The Journal of chemical physics; American Institute of Physics, Melville [NY] (Stati Uniti d'America)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Saija, F; Prestipino, S; Giaquinta, PV (literal)
Pagina inizio
  • 7586 (literal)
Pagina fine
  • 7591 (literal)
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  • 115 (literal)
Rivista
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  • 6 (literal)
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  • 16 (literal)
Note
  • Scopu (literal)
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR-Istituto di Tecniche Spettroscopiche, Messina, Italy Dip. Fisica, Universita' di Messina, Messina, Italy (literal)
Titolo
  • Scaling of local density correlations in a fluid close to freezing (literal)
Abstract
  • We simulated the equilibrium properties of some reference model fluids, with hard-core, Yukawa and Lennard-Jones interactions, and compared their local density profiles in thermodynamic states where the residual multiparticle entropy ~RMPE!, an established and rather sensitive indicator of the incipient ordering of the fluid into a more structured phase, happens to vanish. We found that, once interparticle distances have been referred to the average separation between nearest-neighbor particles, the radial distribution functions ~RDF! coalesce—from the second coordination shell onwards—onto nearly the same spatial profile. This property was ascertained for different model systems in different thermodynamic conditions but for the shared zero-RMPE constraint. The emergence of a scaling relation for the RDF’s in the fluid phase further enlightens the nature of the structural condition that is singled out by the vanishing of the RMPE. (literal)
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