http://www.cnr.it/ontology/cnr/individuo/prodotto/ID40471
Scaling of local density correlations in a fluid close to freezing (Articolo in rivista)
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- Scaling of local density correlations in a fluid close to freezing (Articolo in rivista) (literal)
- Anno
- 2001-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1063/1.1406528 (literal)
- Alternative label
Saija, F; Prestipino, S; Giaquinta, PV (2001)
Scaling of local density correlations in a fluid close to freezing
in The Journal of chemical physics; American Institute of Physics, Melville [NY] (Stati Uniti d'America)
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- Saija, F; Prestipino, S; Giaquinta, PV (literal)
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- CNR-Istituto di Tecniche Spettroscopiche, Messina, Italy
Dip. Fisica, Universita' di Messina, Messina, Italy (literal)
- Titolo
- Scaling of local density correlations in a fluid close to freezing (literal)
- Abstract
- We simulated the equilibrium properties of some reference model fluids, with hard-core, Yukawa and Lennard-Jones interactions, and compared their local density profiles in thermodynamic states where the residual multiparticle entropy ~RMPE!, an established and rather sensitive indicator of the incipient ordering of the fluid into a more structured phase, happens to vanish. We found that, once interparticle distances have been referred to the average separation between nearest-neighbor particles, the radial distribution functions ~RDF! coalescefrom the second coordination shell onwardsonto nearly the same spatial profile. This property was ascertained for different model systems in different thermodynamic conditions but for the shared zero-RMPE constraint. The emergence of a scaling relation for the RDFs in the fluid phase further enlightens the nature of the structural condition that is singled out by the vanishing of the RMPE. (literal)
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