Photoelectron spectroscopy (PES) study of gas-phase 2,5-(2,2'-dithienyl)diethynyl-thiophene (TRIM): an experimental and theoretical study (Articolo in rivista)

Type
Label
  • Photoelectron spectroscopy (PES) study of gas-phase 2,5-(2,2'-dithienyl)diethynyl-thiophene (TRIM): an experimental and theoretical study (Articolo in rivista) (literal)
Anno
  • 2001-01-01T00:00:00+01:00 (literal)
Alternative label
  • G. Polzonetti, V. Carravetta, A. Ferri, P. Altamura, M. Alagia, R. Richter, and M.V. Russo (2001)
    Photoelectron spectroscopy (PES) study of gas-phase 2,5-(2,2'-dithienyl)diethynyl-thiophene (TRIM): an experimental and theoretical study
    in Chemical physics letters (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • G. Polzonetti, V. Carravetta, A. Ferri, P. Altamura, M. Alagia, R. Richter, and M.V. Russo (literal)
Pagina inizio
  • 449 (literal)
Pagina fine
  • 457 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 340 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • Photoelectron spectroscopy (PES) study of gas-phase 2,5-(2,2'-dithienyl)diethynyl-thiophene (TRIM): an experimental and theoretical study (literal)
Abstract
  • The X-ray photoelectron spectra of gaseous 2,5-(2,2 ' -dithienyl:)diethynyl-thiophene (TRIM) in the C is and S 2p core level regions have been recorded by means of synchrotron radiation (SR) at ELETTRA. For all the non-equivalent carbon atoms of TRIM, Delta SCF calculations of the C Is photoelectron spectra, have also been performed. all the carbons of the aromatic rings are perturbed by an electron charge withdrawing. The ethyne carbon atoms are negatively shifted in energy. The relative broadening of the S 2p accounts for the presence of two non-equivalent sulphur atoms. The S 2p(3/2) ionization potential value is lowered with respect to thiophene by -0.63 eV. (literal)
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