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Experimental and theoretical study of resonant Auger decay of core-excited NO2 (Articolo in rivista)
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- Experimental and theoretical study of resonant Auger decay of core-excited NO2 (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Alternative label
M.N. Piancastelli, V. Carravetta, I. Hjelte, A. De Fanis, K. Okada, N. Saito, M. Kitajima, H. Tanaka and K. Ueda (2004)
Experimental and theoretical study of resonant Auger decay of core-excited NO2
in Chemical physics letters (Print)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- M.N. Piancastelli, V. Carravetta, I. Hjelte, A. De Fanis, K. Okada, N. Saito, M. Kitajima, H. Tanaka and K. Ueda (literal)
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- Titolo
- Experimental and theoretical study of resonant Auger decay of core-excited NO2 (literal)
- Abstract
- We have obtained electron decay spectra following core excitation of NO2 below both the nitrogen and the oxygen K-edges. The resonant decay through participator processes is weak below the N K-edge, while is more intense below the O K-edge. The propensity rule stating that two valence electrons tend to participate in the decay with opposite spins was verified in the decay of the O1s->6a1 core excited state and the O1s->2b1 core -excited state(s). Theoretical findings suggest that the relative ordering of the exchange-split core-excited components stems mainly from the valence-valence exchange interaction term being dominant over the core-valence one. (literal)
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